期刊
CHEMICAL ENGINEERING JOURNAL
卷 220, 期 -, 页码 254-263出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.cej.2013.01.003
关键词
SOFC; Dry-reforming; Biogas; Carbon deposition; Re-oxidation
资金
- Engineering and Physical Sciences Research Council [EP/J016454/1] Funding Source: researchfish
- EPSRC [EP/J016454/1] Funding Source: UKRI
The present work investigates the performance and degradation mechanisms of a Ni-based anode supported Solid Oxides Fuel Cells (SOFC) operating at similar to 800 degrees C on direct internal reforming of dry CH4-CO2 mixtures. The catalytic properties of the anode support were first studied in a micro-reactor configuration to determine safe conditions (i.e., without carbon formation) under which a dry conversion of the methane can occur directly within the fuel cell. A full electrochemical characterization of complete cells followed to preliminarily assess their resistance towards carbon formation when operating on direct dry-reforming. Ageing tests of similar to 300 h each have been performed in galvanostatic mode, with impedance spectra taken every 50 h of continuous operation to monitor the trend over the time of the different polarization contributions. Post-mortem microstructural analysis was carried out after each experiment to verify the morphology and nucleation of carbon deposited in the anode electrode. (C) 2013 Elsevier B.V. All rights reserved.
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