期刊
CHEMICAL ENGINEERING JOURNAL
卷 222, 期 -, 页码 426-434出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.cej.2013.02.086
关键词
Catalytic ozonation; Ni/TiO2 catalysts; 2,4-D degradation; Surface interactions
资金
- Department of Graduate Study and Investigation of the National Polytechnic Institute of Mexico [20110185]
- National Council of Science and Technology of Mexico-CONACyT [83593, 83275, 153356]
- UNAM PAPIIT [114209]
Surface modifications of catalysts (TiO2 and Ni/TiO2) were studied after ozonation using isoelectric point determination (IEP) and X-ray photoelectron spectroscopy (XPS) techniques. The catalysts were tested in the degradation of the herbicide 2,4-dichlorophenoxyacetic acid (2,4-D) in aqueous solution. According to the results, the initial activity of Ni/TiO2 catalysts was 26% higher compared with the conventional ozonation. This behavior was explained in terms of a change in the surface chemical composition of the catalysts after ozonation, supported by XPS results in the region O1s and Ti2p. In general, the oxidation of metallic Ni to NiO, the formation of *Ti4+ and *O species in the Ni/TiO2 (P) catalyst, and the presence of abundant -OH groups in the catalytic surface was observed. (C) 2013 Elsevier B.V. All rights reserved.
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