期刊
CHEMICAL ENGINEERING JOURNAL
卷 180, 期 -, 页码 9-18出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.cej.2011.10.085
关键词
Composite photocatalyst; Fe2O3-ZrO2; Chemical stability; Heterogeneous photocatalysis; Organic pollutants
资金
- National Natural Science Foundation of China [50978242]
- National Water Project [2008ZX07516-004]
A new composite photocatalyst (Fe2O3 and ZrO2/Al2O3) combining the properties of both semiconductor and Fenton like catalyst was prepared by loading the Fe2O3 and ZrO2 on an aluminum oxide support through a sol-gel method. The catalyst was characterized by XRD, nitrogen adsorption-desorption, TEM, SEM, ICP-AES, and XPS. The results show that the Fe2O3 and ZrO2 are well loaded on the support, and the crystallite phase composition of the catalyst is alpha-Fe2O3, monoclinic and tetragonal ZrO2 and eta-Al2O3. The catalyst shows high catalytic activity in phenol photodegradation reaction with the phenol conversion efficiency higher than 93% at experimental conditions (catalyst dose, 1.0 g L-1; H2O2 dose, 50 mM; solution pH, 6.0). After two runs of regeneration, the activity of the catalyst shows only a slight decrease. The XPS analysis of the fresh and regenerated catalyst reveals that both the surface elemental composition and their chemical state keep stable. This study presented a new type of photocatalyst for degradation of refractory organic pollutants. (C) 2011 Elsevier B.V. All rights reserved.
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