Article
Pharmacology & Pharmacy
Hector A. Lopez-Munoz, Mauricio Lopez-Romero, Moises A. Franco-Molina, Alejandro Manzano-Ramirez, Cristina Velasquillo, Beatriz Liliana Espana-Sanchez, Ana Laura Martinez-Hernandez, Hayde Vergara-Castaneda, Astrid Giraldo-Betancur, Sarai Favela, Rogelio Rodriguez-Rodriguez, Juan Carlos Mixteco, Juan Carlos Tapia-Picazo, Diana G. Zarate-Trivino, Evgeny Prokhorov, Gabriel Luna-Barcenas
Summary: In this study, we synthesized Au nanoparticles (AuNPs) in chitosan (CTS) solution through chemical reduction of HAuCl4. CTS was further functionalized with glycidyl methacrylate (chitosan-g-glycidyl methacrylate/AuNP, CTS-g-GMA/AuNP) to improve the mechanical properties for cellular regeneration. Our nanocomposites showed excellent cellular viability and had a positive effect on cytokine regulation in the inflammatory and anti-inflammatory response of skin cells. After 40 days, the nanocomposite films exhibited better skin wound healing capacity and cosmetic aspects in comparison with a commercial film and the presence of collagen in the nanocomposite played a significant role in enhancing the overall regeneration effect of skin. Electrical percolation phenomena were utilized to optimize the performance of nanocomposites. Overall, chitosan-based Au nanocomposites showed great potential for skin wound repair.
Article
Chemistry, Multidisciplinary
Bastian Haehnle, Philipp A. Schuster, Lisa Chen, Alexander J. C. Kuehne
Summary: A synthetic toolbox has been developed to create monodisperse core-shell and core-shell-shell particles composed entirely of different types of conjugated polymers. Seeded and fed-batch dispersion polymerizations based on Suzuki-Miyaura-type cross-coupling allow precise control over the interface between conjugated polymer phases, facilitating control over energy transfer phenomena. This new approach offers synthetic freedom for fine-tuning the optical properties of CPP, potentially enabling the synthesis of individual white light-emitting particles.
Article
Polymer Science
Xin Zheng, Lina He, Guipeng Yu, Yongjin Li
Summary: Tea polyphenols (C) can promote the grafting of GMA onto PP chains, but also lead to degradation of the PP backbone. Co-grafting of GMA and tea polyphenols (C) improves the properties of the PP matrix.
Article
Chemistry, Physical
Haifeng Zhou, Bowu Zhang, Weihua Liu, Yanling Xue, Changwei Zhao, Xiaodong Zhang, Xiuhai Cui, Zhongfeng Tang
Summary: In this study, a new method was explored to graft glycidyl methacrylate (GMA) onto the surface of high-modulus carbon fiber (HMCF), which has extremely high chemical inertness. GMA was successfully grafted onto HMCF after acid activation synergized with ionization radiation, with a grafting degree of 22%. The hydrophilicity of the fiber was effectively improved after acid activation and grafting, and it showed good dispersibility in water. The surface structure of the fiber became highly disordered after grafting GMA. This work provides a new pathway for the modification of HMCF and is beneficial for obtaining high performance HMCF composites.
APPLIED SURFACE SCIENCE
(2023)
Article
Materials Science, Ceramics
Wondu Lee, Jaehyun Wie, Jooheon Kim
Summary: In this study, surface modification of aluminum oxide with polymer grafting significantly enhanced the thermal conductivity of the composites.
CERAMICS INTERNATIONAL
(2021)
Article
Chemistry, Multidisciplinary
Elena Vismara, Giulia Bertolini, Chiara Bongio, Nicolo Massironi, Marco Zarattini, Daniele Nanni, Cesare Cosentino, Giangiacomo Torri
Summary: The study showed that nanocellulose recovered from industrial cotton waste has the potential to adsorb antibiotics and disinfectants, with crystalline nanocellulose exhibiting better adsorption performance compared to amorphous nanocellulose. Additionally, the loaded nanocellulose derivatives showed long lasting release capability against certain bacteria, suggesting their potential use in environmental and biomedical applications. The reactivity of nanocellulose with acidic, glycidyl, and allyl groups could lead to the development of other nanocellulose materials in the future.
Article
Optics
Nicola Pellizzi, Alfredo Mazzulla, Pasquale Pagliusi, Gabriella Cipparrone
Summary: The development of efficient and cost-effective micromachines is a challenge for applied and fundamental science. The rotational dynamics of core-shell particles with specific architecture when irradiated by light has been studied, providing important insights for optimizing the design of light controlled micro-objects.
PHOTONICS RESEARCH
(2022)
Article
Food Science & Technology
Fei-Yue Xu, Jia-Wei Lin, Rui Wang, Bo-Ru Chen, Jian Li, Qing-Hui Wen, Xin-An Zeng
Summary: By combining proteins with chitosan, changes in zeta-potential and surface hydrophobicity were observed, leading to the protection of curcumin. Structural changes were analyzed using FTIR, CD, and XRD techniques. The H-CS composite particles showed enhanced stability of curcumin, especially in terms of photostability and thermo-stability.
FOOD RESEARCH INTERNATIONAL
(2022)
Article
Chemistry, Applied
Maoli Yin, Xia Li, Ying Liu, Xuehong Ren
Summary: A novel family of chitosan-based cryogels with antibacterial activity was constructed in this study for treating different types of dye wastewater. These cryogels showed high removal efficiency for dye pollutants and exhibited great potential for the remediation of dyeing wastewater.
CARBOHYDRATE POLYMERS
(2021)
Article
Chemistry, Multidisciplinary
Jia Xia, Xia Luo, Jin Huang, Jiajun Ma, Junxiao Yang
Summary: By utilizing core/shell organic-inorganic hybrid polymer nanoparticles to toughen PMMA, incorporating silicone as a toughening agent and chain extender enhances the mechanical properties of PMMA/ASA alloys, particularly with significantly improved impact strength and elongation at break after adding silicone-modified ASA.
Article
Polymer Science
Vitalia M. Yartseva, Olga A. Makevnina, Ekaterina B. Bryuzgina, Evgeny Bryuzgin, Viktor V. Klimov, Olga Kolyaganova, Dmitry E. Nikolitchev, Alexander Navrotsky, Ivan A. Novakov
Summary: This paper discusses the influence of copolymer structure on the wettability and sorption properties of surface-modified chitosan aerogels. The results show that increasing the amount of alkyl methacrylates leads to enhanced hydrophobicity and decreased water absorption, while maintaining high sorption capacity for light oil and synthetic motor oil.
Article
Chemistry, Multidisciplinary
Frederique A. Versteeg, Benedicta B. Benita, Jesse A. Jongstra, Francesco Picchioni
Summary: This study designed a new adhesive with better mechanical properties by grafting glycidyl methacrylate (GMA) onto (recycled) polyethylene (PE). The results showed that higher amounts of GMA led to higher functionalization degrees (FD), while higher amounts of dicumyl peroxide (DCP) resulted in lower FD due to more unfavorable side reactions. The influence of supercritical carbon dioxide (scCO(2)) on FD varied depending on the substrates used. Adjusting the screw speed and temperature profile had the highest positive impact on FD. All the grafted samples, especially the grafted RPE, showed higher stress levels compared to the non-grafted samples.
APPLIED SCIENCES-BASEL
(2022)
Article
Materials Science, Multidisciplinary
Samin Habibi, Steven Bryant, Roman Shor, Giovanniantonio Natale
Summary: The study focuses on creating monodisperse magnetic particles by depositing a magnetite layer on the surface of silica particles using a low-temperature electroless deposition technique. This technique, scalable and suitable for mass production, can be applied to a wide range of inorganic materials or polymer particles. The resulting SiO2@Fe3O4 core/shell particle is responsive to magnetic fields and shows promise for applications in magnetorheological fluids.
MATERIALS CHEMISTRY AND PHYSICS
(2022)
Article
Chemistry, Multidisciplinary
Adriano Santos Silva, Jose Luis Diaz de Tuesta, Thais Sayuri Berberich, Simone Delezuk Inglez, Ana Raquel Bertao, Ihsan Caha, Francis Leonard Deepak, Manuel Banobre-Lopez, Helder Teixeira Gomes
Summary: Magnetic nanoparticles have been widely used in various fields such as environmental and biomedical applications. The ability to design nanoparticles with different functionalities and use magnetic fields for targeted delivery has further advanced their biomedical applications. The development of multi-core shell magnetic nanoparticles as drug carriers for cancer treatment has gained increasing attention. However, the synthesis of nanoparticles with high colloidal stability, triggered drug release, and good biocompatibility remains a challenge.
Article
Chemistry, Multidisciplinary
Maria Antonieta Ramirez-Morales, Anastasia E. Goldt, Polina M. Kalachikova, Javier A. B. Ramirez, Masashi Suzuki, Alexey N. Zhigach, Asma Ben Salah, Liliya Shurygina, Sergey D. Shandakov, Timofei Zatsepin, Dmitry Krasnikov, Toru Maekawa, Evgeny N. Nikolaev, Albert G. Nasibulin
Summary: Carbon-encapsulated iron nanoparticles with a mean diameter of 15 nm were synthesized using a gas-phase reaction at high temperatures. The nanoparticles were stabilized with a coating and showed high specific absorption rate (SAR), making them suitable for magnetic hyperthermia therapy.
Article
Chemistry, Applied
Corneliu Hamciuc, Tachita Vlad-Bubulac, Diana Serbezeanu, Gabriela Lisa, Ion Anghel, Dana Maria Preda
Summary: In this study, a novel polyphosphonate and halloysite nanotubes were incorporated into epoxy resin to prepare environmental-friendly nanocomposites with improved flame retardancy.
JOURNAL OF VINYL & ADDITIVE TECHNOLOGY
(2023)
Article
Biochemistry & Molecular Biology
Parinaz Hobbi, Oseweuba Valentine Okoro, Maryam Hajiabbas, Masoud Hamidi, Lei Nie, Veronique Megalizzi, Paul Musonge, Gianina Dodi, Amin Shavandi
Summary: Apple pomace (AP) from the food industry contains bioactive polyphenolic compounds. This study focuses on the recovery and evaluation of these compounds from different fractions of AP. Subcritical water extraction showed higher total polyphenolic compounds (39.08 mg GAE/g db) compared to ethanol extraction (10.78 mg GAE/g db). HPLC analysis identified phloridzin, chlorogenic acid, and quercetin as the main polyphenolics in AP.
Article
Materials Science, Multidisciplinary
Alin Grig Mihis, Liviu Cosmin Cotet, Calin Cadar, Lucian Cristian Pop, Milica Todea, Mihai Marius Rusu, Adriana Vulpoi, Istvan Szekely, Catalin Alexandru Salagean, Klara Magyari, Marieta Muresan-Pop, Oana Cadar, Monica Baia, Ioana Emilia Sofran, Gabriela Lisa, Ion Anghel, Mihaela Baibarac, Virginia Danciu, Lucian Baia
Summary: A multi-structure synergistic composite was synthesized by grafting a novel nitrogen-containing polyhedral oligomeric silsesquioxane (HAK) and 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide (DOPO) on the surface of graphene oxide (GO) nanosheet for the development of flame retardants materials. The functionalization of GO with DOPO, and then with HAK was confirmed, and the GO-DOPO-HAK showed great potential as a flame retardant material with significant decrease in heat release capacity and increased char yield.
JOURNAL OF MATERIALS SCIENCE
(2023)
Article
Materials Science, Biomaterials
Mahta Mirzaei, Gianina Dodi, Ioannis Gardikiotis, Sorin-Aurelian Pasca, Saeed Mirdamadi, Gilles Subra, Cecile Echalier, Chloe Puel, Rino Morent, Rouba Ghobeira, Nazila Soleymanzadeh, Muriel Moser, Stanislas Goriely, Amin Shavandi
Summary: In this study, melt electro written (MEW) scaffolds of poly(e-caprolactone) PCL were decorated with anti-inflammatory yeast-derived peptide for skin wound healing. Thirteen different yeast-derived peptides were screened and analyzed using in vitro and in vivo assays. The selected peptide VLSTSFPPW (VW-9) was conjugated to the MEW scaffolds using carbodiimide (CDI) and thiol chemistry, with and without plasma treatment, as well as by directly mixing the peptide with the polymer before printing. The peptide-modified MEW scaffolds showed improved fibroblast and macrophage penetration and adhesion, increased cell proliferation, and superior anti-inflammatory properties.
BIOMATERIALS ADVANCES
(2023)
Article
Polymer Science
Florina-Daniela Cojocaru, Ioannis Gardikiotis, Gianina Dodi, Aurelian Rotaru, Vera Balan, Elena Rezus, Liliana Verestiuc
Summary: The increasing tendency of population aging is directly correlated with a significant number of associated pathologies. Implantable bone substitutes have proven to be an efficient solution for metabolic bone diseases such as osteoporosis or chronic kidney disease-mineral and bone disorders. This study aimed to develop composite beads with a combination of biopolymers (specifically alginate and guar gum/carboxymethyl guar gum) and ceramics (specifically calcium phosphates). The results showed that the beads based on a higher concentration of guar gum had superior properties for bone tissue repair.
Article
Polymer Science
Tachita Vlad-Bubulac, Corneliu Hamciuc, Diana Serbezeanu, Dana Mihaela Suflet, Daniela Rusu, Gabriela Lisa, Ion Anghel, Dana-Maria Preda, Totka Todorova, Cristina Mihaela Rimbu
Summary: This study investigates the preparation and properties of semi-interpenetrated nanocomposite films based on poly(vinyl alcohol) crosslinked with oxalic acid, reinforced with a flame retardant and silver-loaded zeolite nanoparticles. Scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDX) analysis reveals the homogeneous distribution of the flame retardant and nanoparticles within the composite films. The flame retardancy of the composites remarkably improved with low phosphorus content, and the reinforced nanocomposites showed significant increases in tensile strength and elastic modulus. Additionally, samples containing silver-loaded zeolite nanoparticles exhibited enhanced antimicrobial activity.
Article
Polymer Science
Andreea Irina Barzic, Ion Sava, Raluca Marinica Albu, Cristian Ursu, Gabriela Lisa, Iuliana Stoica
Summary: This article explores the potential use of polyimide-based films as a recording medium for optical storage devices. It was found that the addition of azo dye can improve the performance of polyimide-based films, such as vitrification temperature, colorimetric features, refractive index, and optical conductivity.
Article
Green & Sustainable Science & Technology
Mariana Ichim, Ioan Filip, Lucia Stelea, Gabriela Lisa, Emil Ioan Muresan
Summary: The aim of this study is to investigate the effects of incorporating recycled fibers and a compatibilizer on the properties of composite materials. The results showed that the inclusion of recycled fibers decreased the tensile strength, elongation at break, flexural strength, and flexural modulus of the composites. However, the addition of a compatibilizer improved the mechanical properties of the composites containing 100% recycled fibers. Thermal analysis revealed good thermal stability of the composites, and SEM and EDX analysis confirmed the presence of the compatibilizing agent in the composite structure.
Article
Medicine, General & Internal
Carina Ureche, Gianina Dodi, Alexandra Covic, Alina Nedelcu, Simona R. Volovat, Radu A. Sascau, Cristian Statescu, Adrian Covic
Summary: This study aimed to determine the association between echocardiographic parameters and biomarkers of cardiac fibrosis in patients with end-stage renal disease. The results showed a significant correlation between echocardiographic parameters and biomarkers, especially a strong association between the collagen-derived biomarker PICP and cardiac function indicators.
JOURNAL OF CLINICAL MEDICINE
(2023)
Article
Biochemistry & Molecular Biology
Carina Ureche, Gianina Dodi, Adela Mihaela Serban, Andreea Simona Covic, Luminita Voroneanu, Simona Hogas, Radu Andy Sascau, Cristian Statescu, Adrian Covic
Summary: Patients with chronic kidney disease have an increased risk of death, and collagen biomarkers such as PICP may be valuable in predicting mortality in ESRD patients.
Article
Biochemistry & Molecular Biology
Julia Simi Simnska-Stanny, Feza Hachemi, Gianina Dodi, Florina D. Cojocaru, Ioannis Gardikiotis, Daria Podstawczyk, Christine Delporte, Guohua Jiang, Lei Nie, Amin Shavandi
Summary: In this study, a printable biomaterial ink for 3D printing of shape-maintaining hydrogel scaffolds was developed. The ink was composed of tyramine-modified hyaluronic acid (HA-Tyr) and gelatin methacrylate (GelMA), and was dually cross-linked. By adjusting the polymer ratios, a stable hydrogel with varying responses was produced, offering precision and flexibility in 3D printing. The ink exhibited shearthinning behavior and high swelling capacity, making it an ideal candidate for soft tissue matrices with ECM-like characteristics and biocompatibility.
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
(2023)
Article
Biochemistry & Molecular Biology
Tachita Vlad-Bubulac, Corneliu Hamciuc, Diana Serbezeanu, Ana-Maria Macsim, Gabriela Lisa, Ion Anghel, Dana-Maria Preda, Yuri Kalvachev, Cristina Mihaela Rimbu
Summary: The design and manufacture of innovative multifunctional materials with superior characteristics and standards are crucial for the future development of advanced technologies. Adjusting the properties of epoxy resins using organophosphorus compounds and silver-containing additives can improve their flame-resistant and antimicrobial properties.
Article
Biochemistry & Molecular Biology
Diana Serbezeanu, Corneliu Hamciuc, Tachita Vlad-Bubulac, Alina-Mirela Ipate, Gabriela Lisa, Ina Turcan, Marius Andrei Olariu, Ion Anghel, Dana Maria Preda
Summary: Flame-resistant polymer composites were prepared by incorporating flame retardant, cerium oxide, and graphene oxide into a polyvinyl alcohol (PVA) matrix. Thermogravimetric analysis and microscale combustion tests showed improved fire resistance properties due to the addition of these materials. Moreover, composites with LiClO4 exhibited higher electrical conductivity and enhanced electrical properties. Taking these findings into consideration, these improved polymer composites are intended for use in Li-ion battery manufacturing.
Article
Biochemical Research Methods
Andreea Creteanu, Gabriela Lisa, Cornelia Vasile, Maria-Cristina Popescu, Adrian Florin Spac, Gladiola Tantaru
Summary: This study aimed to improve the solubility of amiodarone by encapsulating it into solid lipid nanoparticles using Compritol(R) 888 ATO (pellets) (C888) as a lipid matrix and Transcutol(R) (T) as a surfactant. Among the tested formulations, P5 showed the most favorable pharmaco-technical properties and the potential for controlled delivery of amiodarone in oral pharmaceutical products.
METHODS AND PROTOCOLS
(2023)
Article
Biochemistry & Molecular Biology
Mihai Asandulesa, Corneliu Hamciuc, Aurel Pui, Constantin Virlan, Gabriela Lisa, Andreea Irina Barzic, Bogdan Oprisan
Summary: This article presents the development of new composites based on a PEI matrix and CoFe2O4 nanoparticles. These composites exhibit high thermal stability and increased conductivity compared to pure PEI. The composites also show potential for attenuating the electric and magnetic parts of electromagnetic waves, making them suitable for EMI shielding applications.
INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES
(2023)
Article
Engineering, Environmental
Xinping Zhang, Yuxin Guo, Xiaoyang Liu, Shun-Yu Wu, Ya-Xuan Zhu, Shao-Zhe Wang, Qiu-Yi Duan, Ke-Fei Xu, Zi-Heng Li, Xiao-Yu Zhu, Guang-Yu Pan, Fu-Gen Wu
Summary: This study develops a nanotrigger HCFT for simultaneous photodynamic therapy and light-triggered ferroptosis therapy. The nanotrigger can relieve tumor hypoxia, induce enhanced photodynamic reaction, and facilitate the continuation of Fenton reaction, ultimately leading to lethal ferroptosis in tumor cells.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Olumide Bolarinwa Ayodele, Toyin Daniel Shittu, Olayinka S. Togunwa, Dan Yu, Zhen-Yu Tian
Summary: This study focused on the semihydrogenation of acetylene in an ethylene-rich stream using two alloyed Pt catalysts PtCu and PtCo. The PtCu catalyst showed higher activity and ethylene yield compared to PtCo due to its higher unoccupied Pt d-orbital density. This indicates that alloying Pt with Cu is more promising for industrial relevant SHA catalyst.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Guowei Chen, Wen-Cheng Chen, Yaozu Su, Ruicheng Wang, Jia-Ming Jin, Hui Liang, Bingxue Tan, Dehua Hu, Shaomin Ji, Hao-Li Zhang, Yanping Huo, Yuguang Ma
Summary: This study proposes an intramolecular dual-locking design for organic luminescent materials, achieving high luminescence efficiency and performance for deep-blue organic light-emitting diodes. The material also exhibits unique mechanochromic luminescence behavior and strong fatigue resistance.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Joren van Stee, Gregory Hermans, Jinu Joseph John, Koen Binnemans, Tom Van Gerven
Summary: This work presents a continuous solvent extraction method for the separation of cobalt and nickel in a millifluidic system using Cyphos IL 101 (C101) as the extractant. The optimal conditions for extraction performance and solvent properties were determined by investigating the effects of channel length, flow rate, and temperature. The performance of a developed manifold structure was compared to a single-channel system, and excellent separation results were achieved. The continuous separation process using the manifold structure resulted in high purity cobalt and nickel products.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Yan Xu, Jingai Jiang, Xinyi Lv, Hui Li, Dongliang Yang, Wenjun Wang, Yanling Hu, Longcai Liu, Xiaochen Dong, Yu Cai
Summary: A programmed gas release nanoparticle was developed to address the challenges in treating diabetic infected wounds. It effectively removes drug-resistant pathogens and remodels the wound microenvironment using NO and H2S. The nanoparticle can eliminate bacteria and promote wound healing through antibacterial and anti-inflammatory effects.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Tong Xia, Zhilin Xi, Lianquan Suo, Chen Wang
Summary: This study investigated a highly efficient coal dust suppressant with low initial viscosity and high adhesion-solidification properties. The results demonstrated that the dust suppressant formed a network of multiple hydrogen bonding cross-linking and achieved effective adhesion and solidification of coal dust through various chemical reactions.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Jinzhi Cai, Zhenshan Li
Summary: A density functional theory-based rate equation was developed to predict the gas-solid reaction kinetics of CaO carbonation with CO2 in calcium looping. The negative activation energy of CaO carbonation close to equilibrium was accurately predicted through experimental validation.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Jianxiong Chen, Fuhao Ren, Ningning Yin, Jie Mao
Summary: This study presents an economically efficient and easily implementable surface modification approach to enhance the high-temperature electrical insulation and energy storage performance of polymer dielectrics. The self-assembly of high-insulation-performance boron nitride nanosheets (BNNS) on the film surface through electrostatic interactions effectively impedes charge injection from electrodes while promoting charge dissipation and heat transfer.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Zijian Li, Zhaohui Yang, Shao Wang, Hongxia Luo, Zhimin Xue, Zhenghui Liu, Tiancheng Mu
Summary: This study reports a strategy for upgrading polyester plastics into value-added chemicals using electrocatalytic methods. By inducing the targeted transfer of *OH species, polyethylene terephthalate was successfully upgraded into potassium diformate with high purity. This work not only develops an excellent electrocatalyst, but also provides guidance for the design of medium entropy metal oxides.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Navneet Singh Shekhawat, Surendra Kumar Patra, Ashok Kumar Patra, Bamaprasad Bag
Summary: This study primarily focuses on developing a sulphur dyeing process at room temperature using bacterial Lysate, which is environmentally friendly, energy and cost effective, and sustainable. The process shows promising improvements in dye uptake and fastness properties.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Dengjia Shen, Hongyang Ma, Madani Khan, Benjamin S. Hsiao
Summary: This study developed cationic PVC nanofibrous membranes with high filtration and adsorption capability for the removal of bacteria and hexavalent chromium ions from wastewater. The membranes demonstrated remarkable performance in terms of filtration efficiency and maximum adsorption capacity. Additionally, modified nanofibrous membranes were produced using recycled materials and showed excellent retention rates in dynamic adsorption processes.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Xiaoyan Wang, Zhikun Wang, Ben Jia, Chunling Li, Shuangqing Sun, Songqing Hu
Summary: Inspired by photosystem II, self-supported Fe-doped NiCoP nanowire arrays modified with carboxylate were constructed to boost industrial-level overall water splitting by employing the concerted proton-coupled electron transfer mechanism. The introduction of Fe and carboxyl ligand led to improved catalytic activity for HER and OER, and NCFCP@NF exhibited long-term durability for overall water splitting.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Pengyao Yu, Ge Yang, Yongming Chai, Lubomira Tosheva, Chunzheng Wang, Heqing Jiang, Chenguang Liu, Hailing Guo
Summary: Thin LTA zeolite membranes were prepared through secondary growth of nano LTA seeds in a highly reactive gel, resulting in membranes with superior permeability and selectivity in gas separation applications.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Baiqin Zhou, Huiping Li, Ziyu Wang, Hui Huang, Yujun Wang, Ruichun Yang, Ranran Huo, Xiaoyan Xu, Ting Zhou, Xiaochen Dong
Summary: The use of machine learning to predict the performance of specific adsorbents in phosphate adsorption shows great promise in saving time and revealing underlying mechanisms. However, the small size of the dataset and insufficient detailed information limits the model training process and the accuracy of results. To address this, the study employs a fuzzing strategy that replaces detailed numeric information with descriptive text messages on the physiochemical properties of adsorbents. This strategy allows the recovery of discarded samples with limited information, leading to accurate prediction of adsorption amount, capacity, and kinetics. The study also finds that phosphate uptake by adsorbents is generally through physisorption, with some involvement of chemisorption. The framework established in this study provides a practical approach for quickly predicting phosphate adsorption performance in urgent scenarios, using easily accessible information.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Paula Alejandra Lamprea Pineda, Joren Bruneel, Kristof Demeestere, Lisa Deraedt, Tex Goetschalckx, Herman Van Langenhove, Christophe Walgraeve
Summary: This study evaluates the use of four esterified fatty acids and three vegetable oils as absorption liquids for hydrophobic VOCs. The experimental results show that isopropyl myristate is the most efficient liquid for absorbing the target VOCs.
CHEMICAL ENGINEERING JOURNAL
(2024)