4.7 Article

Mesoporous Cu2O submicro-spheres, facile synthesis and the selective adsorption properties

期刊

CHEMICAL ENGINEERING JOURNAL
卷 185, 期 -, 页码 151-159

出版社

ELSEVIER SCIENCE SA
DOI: 10.1016/j.cej.2012.01.064

关键词

Selective adsorption; Mesoporous Cu2O submicro-spheres; Adsorption isotherm; Kinetics

资金

  1. Natural Science Foundation of China [61176004]
  2. Basic and Frontier Research Programs of Henan Province [092300410194]
  3. Science and Technology Breakthrough Program of Henan Province [112300410094]
  4. Natural Science Foundation of Education Department of Henan Province [2010B150012, 2011A150017]

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Mesoporous Cu2O submicro-spheres with average size of 300 nm and specific surface area of 58 m(2) g(-1) were synthesized via a simple process at room temperature. The resulting product was found to have high affinity to anionic methylene orange (MO) and can be employed to selectively adsorb MO from mixture consisted of different dyes. The adsorption capacity of the mesoporous Cu2O submicro-spheres for MO is estimated to be 48.38 mg g(-1), the adsorption kinetics obeys pseudo-second-order kinetics following the Freundlich isotherm. The effective desorption of MO by controlling proper ionic strength approves the potential applications of the mesoporous Cu2O submicro-spheres as adsorbent for treatments of dye containing effluents. (c) 2012 Elsevier B.V. All rights reserved.

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