Review
Engineering, Environmental
Ting Liu, Zhuo Xiong, Peng Ni, Zizhen Ma, Yan Tan, Zishun Li, Shengnan Deng, Yincui Li, Qirong Yang, Huawei Zhang
Summary: This review focuses on the current situation of Hg0 removal on different kinds of adsorbents in coal combustion flue gas, smelting flue gas, and natural gas. Hydrophobic groups, hydrophobic materials, and modification of sulfur/selenium pretreatment and metals loading can effectively overcome the problem of H2O and SO2. Additionally, separation, regeneration, and recovery aspects are explored and summarized, with thermal treatment accompanied by different components being widely adopted as an efficient approach to recover the adsorption ability.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Engineering, Environmental
Feng Xin, Rihong Xiao, Yongchun Zhao, Junying Zhang
Summary: This research proposes a method to reduce elemental mercury emission from coal-fired power plants by modifying magnetospheres with H2S as a sorbent. The modified magnetospheres show high affinity towards Hg-0 and can achieve over 80% adsorption efficiency. The technology has low cost, high recyclability, and minimal impact on environmental mercury pollution.
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
Engineering, Environmental
Jianping Yang, Yuanyuan Na, Yingchao Hu, Penglin Zhu, Fanyue Meng, Qingjie Guo, Zequn Yang, Wenqi Qu, Hailong Li
Summary: Circulating adsorbents integrating elemental mercury adsorption and oxidized mercury decomposition/desorption processes were used for simultaneous adsorbent recycling and mercury recovery. The formation of granulated adsorbent pellets reduced elutriation in the system. La0.8Ce0.2MnO3 perovskite adsorbent was molded into pellets using an extrusion-spheronization method with microcrystalline cellulose (MC) as a pore-creating template. The pellets showed excellent Hg0 removal efficiency and durability in a wide temperature range, with slight interference from SO2 and H2O and enhancement from O2 and NO. The presence of pore channels in the pellets allowed for efficient Hg0 diffusion and in-situ retention during high-temperature burning.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Energy & Fuels
Jianping Yang, Qin Li, Wenbing Zhu, Wenqi Qu, Min Li, Zhengyong Xu, Zequn Yang, Hui Liu, Hailong Li
Summary: This study utilized the abundant mineral chalcopyrite as an efficient trap for Hg-0 sequestration, showing excellent removal performance in a wide temperature range and minimal interference from typical flue gas components. The adsorption capacity and rate of CuFeS2 were significantly higher than commercial activated carbons, attributed to the oxidizing and immobilizing abilities of disulfide ligands, and the sorbent could be regenerated through thermal decomposition, saving operation costs. CuFeS2 is identified as a potential, cost-effective trap for efficient remediation of Hg-0 from coal combustion flue gas.
Article
Engineering, Environmental
Wei Zheng, Zequn Yang, Wenqi Qu, Jianwei Huang, Weizhen He, Jianping Yang, Wanliang Yang, Mengkui Tian, Zhengyong Xu, Hailong Li
Summary: In this study, a feasible synthesis strategy based on mechanical ball-milling procedure was proposed to synthesize (001) surface exposed CuS with high Hg0 adsorption capacity. The controllable nucleus formation and favorable crystalline growth manner under mechanochemical condition resulted in well-structured CuS nanosheets containing abundant under-coordinated sulfur ligands, ensuring the adequate exposure of active sites. The CuS nanosheets showed exceptional Hg0 adsorption capacity and uptake rate, surpassing previous benchmark metal sulfides.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Engineering, Environmental
Lu Dong, Hai Wang, Yaji Huang, Jianrui Zha, Haoqiang Cheng, Lingqin Liu, Zhicheng Zhu, Hao Chen, Shouyi Ding, Sheng Wang
Summary: A magnetically recoverable sorbent incorporating γ-Fe2O3 into attapulgite and loaded with CuCl2 was developed for efficient removal of Hg-0 from coal combustion flue gas. The sorbent showed promising results in Hg-0 removal at high temperature, with the mechanism involving O-2 regeneration and Cu/Fe re-oxidation. The sorbent was less affected by NO and SO2, and the presence of HCl and O-2 aided in regeneration for multiple cycles.
CHEMICAL ENGINEERING JOURNAL
(2021)
Review
Engineering, Environmental
Wei Zheng, Hailong Li, Zequn Yang, Jianping Yang, Wenqi Qu, Fanyue Meng, Yong Feng, Zhengyong Xu, Xueyi Guo
Summary: This review highlights the global concerns over mercury contamination and the advantages of mineral chalcogenides in immobilizing gaseous elemental mercury. It provides an overview of research progress and application conditions of mineral chalcogenides for Hg-0 removal, as well as comparisons of their adsorption performance. Comprehensive discussions on influential factors and mechanisms for Hg-0 removal by different mineral chalcogenides are also presented to guide future research directions.
CHEMICAL ENGINEERING JOURNAL
(2021)
Article
Energy & Fuels
Huan Liu, Zhuo Xiong, Rong Peng, Bengen Gong, Lin Chang, Jianping Yang, Yongchun Zhao, Junying Zhang
Summary: The study investigated the efficacy of CuBr2-TCS as an adsorbent for removing Hg-0 in simulated coal-fired flue gas, demonstrating high removal efficiency. The in-depth exploration of Hg-0 removal performance under different flue gas components proved that CuBr2-TCS has a good removal effect on Hg-0.
Review
Green & Sustainable Science & Technology
Alhadi Ishag, Yanxue Yue, Jingting Xiao, Xinshui Huang, Yubing Sun
Summary: This article reviews recent advances in the adsorption and oxidation of mercury from coal-fired flue gases, including the mechanisms of adsorption and catalytic oxidation under different environmental conditions. It also addresses current challenges and future research directions.
JOURNAL OF CLEANER PRODUCTION
(2022)
Article
Engineering, Environmental
Zifeng Luo, Tao Jia, Qianyan Liu, Yubao Song, Min Zhou, Xinxia Ma, Jiang Wu, Zhiwei Qin, Xuefei Wu
Summary: CIS/GCN sorbents, with abundant surface metal cation vacancies and sulfur sites, demonstrated excellent Hg0 removal performance and are considered a strong candidate for current commercial activated carbon.
CHEMICAL ENGINEERING JOURNAL
(2021)
Article
Chemistry, Physical
Yang Teng, Peixuan Li, Guangyu Wang, Chen Wang, Nana Qi, Kai Zhang, Minwu Wang
Summary: Field testing at a 300 MW coal-fired power station showed that selective catalytic reduction (SCR) can effectively reduce mercury content in flue gas. Commercial testing demonstrated that SCR catalyst breakage resulted in an increase in total mercury concentration at the electrostatic precipitator (ESP) inlet and outlet. Laboratory experiments confirmed the Hg0 oxidation capability of the commercial SCR catalyst.
APPLIED CATALYSIS A-GENERAL
(2023)
Article
Energy & Fuels
Xin Huang, Zijun Ran, Zhi He, Jingyu Ran
Summary: Mercury, mainly derived from coal-fired power plants, has a significant impact on the environment. In this study, we propose a potential method for efficient removal of Hg0 through oxidation reactions using Ce-doped LaCoO3 supported on CeO2 catalyst. The catalyst characterization results confirm the successful substitution of Co with Ce in the LaCoO3 crystal lattice. The Hg0 removal experiments demonstrate that the La0.875Ce0.125CoO3/CeO2 catalyst exhibits the highest removal efficiency, and the presence of O2 greatly enhances its effectiveness. The addition of H2O and SO2 reduces the Hg0 removal efficiency due to competitive adsorption, but the presence of O2 allows SO2 to react with Hg0 and recover the efficiency.
Article
Engineering, Environmental
Dong Ye, Xiaoxiang Wang, Runxian Wang, Senyuan Wang, Hui Liu, Haining Wang
Summary: This review discusses the progress in the application of MnO2-based materials for mercury removal, summarizing the fundamentals of MnO2, the properties of various adsorbents, and the effects of gas species on mercury capture capacity. The possible mercury adsorption mechanisms and regeneration methods are also explored, with a suggestion for the development of new MnO2-based adsorbents for future research.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2021)
Article
Engineering, Environmental
Xue-Lei Duan, Chun-Gang Yuan, Qi Guo, Sheng-Li Niu, Kai-Qiang He, Guo-Wei Xia
Summary: A multifunctional core-shell sorbent based on halloysite nanotubes was successfully fabricated and applied for Hg-0 removal from flue gas. The unique structure and composition not only enabled easy separation and reuse, but also significantly enhanced the adsorption capacity and SO2 tolerance of the sorbent.
JOURNAL OF HAZARDOUS MATERIALS
(2021)
Article
Chemistry, Applied
Shilin Zhao, Junlin Peng, Runqi Ge, Siyu Wu, Kehui Zeng, Huajun Huang, Kaibo Yang, Zhiqiang Sun
Summary: This study comprehensively discusses SCR catalysts with different supports, including their preparation method, composition, deNOx ability, etc. The findings show that metal-based SCR catalysts have good performance in both high and low-temperature deNOx, carbon material as a carrier can enhance deNOx ability, and minerals-based SCR catalysts have good deNOx capacity at medium to low temperature. The good distribution of active elements, chemical adsorption, acid sites, and surface pore structure are crucial for the deNOx ability of catalysts.
FUEL PROCESSING TECHNOLOGY
(2022)
Article
Chemistry, Applied
Zichen Du, Fuping Pan, Xiaokun Yang, Lingzhe Fang, Yang Gang, Siyuan Fang, Tao Li, Yun Hang Hu, Ying Li
Summary: In this study, Ni-based catalysts with improved activity and stability for solar-driven photothermochemical dry reforming of methane (PTC-DRM) were developed by supporting Ni nanoparticles on CeO2 incorporated ZrO2. The Ni-CeO2/ZrO2 catalyst exhibited significantly higher production rates of H2 and CO compared to Ce-free Ni/ZrO2. The introduction of CeO2 lowered the activation energies of CH4 and CO2 conversions, and the plasmonic effect from Ni mitigated coke deposition and enhanced the PTC-DRM activities and stability. This study is important for designing cost-effective Ni-based catalysts and reaction systems for greenhouse gases conversion using sustainable solar energy.
Article
Engineering, Environmental
Wei Zheng, Zequn Yang, Wenqi Qu, Jianwei Huang, Weizhen He, Jianping Yang, Wanliang Yang, Mengkui Tian, Zhengyong Xu, Hailong Li
Summary: In this study, a feasible synthesis strategy based on mechanical ball-milling procedure was proposed to synthesize (001) surface exposed CuS with high Hg0 adsorption capacity. The controllable nucleus formation and favorable crystalline growth manner under mechanochemical condition resulted in well-structured CuS nanosheets containing abundant under-coordinated sulfur ligands, ensuring the adequate exposure of active sites. The CuS nanosheets showed exceptional Hg0 adsorption capacity and uptake rate, surpassing previous benchmark metal sulfides.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Chemistry, Multidisciplinary
Zichen Du, Cullen Petru, Xiaokun Yang, Fan Chen, Siyuan Fang, Fuping Pan, Yang Gang, Hong-Cai Zhou, Yun Hang Hu, Ying Li
Summary: In this work, Ce-substituted LaNiO3 perovskite catalysts were used for solar-driven photothermochemical dry reforming of methane. It was found that Ce substitution improved the distribution of Ni active sites, mitigated sintering and carbon formation, and enhanced the reaction rates.
JOURNAL OF CO2 UTILIZATION
(2023)
Article
Engineering, Environmental
Pengcheng Wu, Huoerhute Yelemulati, Shanshan Zhu, Bowen Peng, Hailong Li, Hongyong Ye, Juan Hou, Keliang Wu, Zhiyong Liu
Summary: The construction of oxygen vacancies (Ovs) is an important approach to regulate the electronic structure and catalytic properties of semiconductor materials. In this study, a new method involving in situ B-doping and amorphous-crystalline junction was proposed for constructing riched Ovs to enhance photoelectrocatalytic water oxidation performance. The introduction of B-doping and amorphous-crystalline junction was confirmed to result in a substantial increase in Ovs concentration. DFT calculations and COMSOL simulations revealed that the electric field deviation could promote the charge separation of the composite, thereby improving the catalytic activity.
CHEMICAL ENGINEERING JOURNAL
(2023)
Review
Energy & Fuels
Lijian Leng, Junhui Zhou, Tanghao Li, Mikhail Vlaskin, Hao Zhan, Haoyi Peng, Huajun Huang, Hailong Li
Summary: This study provides an overview of the effects of biomass and HTL processing parameters on the distribution and transformation mechanisms of N-H during HTL of nitrogen-rich biomass. Factors such as biomass composition, HTL process parameters, and extraction conditions were found to influence the formation of N-H. Strategies for optimizing biomass feedstock, HTL process, and N-H analysis were proposed to promote the development in this area, with machine learning-aided prediction and regulation of N-H formation reactions showing promise.
Review
Chemistry, Multidisciplinary
Xuran Ji, Zhijie Shen, Wenping Xu, Shimiao Yao, Hairong Zhang, Lian Xiong, Hailong Li, Haijun Guo, Xuefang Chen, Xinde Chen
Summary: The physical and chemical properties of gold make it suitable for various industries. With the depletion of easily leachable ore, it becomes necessary to extract gold from other resources. Non-cyanide leaching methods have been developed as a safer alternative to cyanide leaching. Among these methods, ion exchange resins have been found to efficiently adsorb gold. This paper focuses on the research progress of using ion exchange resins to recover gold from non-cyanide leachates, discussing existing resin types, elution processes, limitations, and potential solutions.
KOREAN JOURNAL OF CHEMICAL ENGINEERING
(2023)
Article
Chemistry, Multidisciplinary
Yang Gang, John Pellessier, Zichen Du, Siyuan Fang, Lingzhe Fang, Fuping Pan, Manuel Suarez, Kirk Hambleton, Fan Chen, Hong-Cai Zhou, Tao Li, Yun Hang Hu, Ying Li
Summary: This study developed a simple and scalable synthesis method to convert metal-impurity-containing commercial carbon nanotubes (CNTs) and nitrogen-containing organic precursors into metal-and nitrogen-doped carbon (M-N-C) catalysts. The catalysts exhibited high CO selectivity and durability, outperforming benchmark catalysts and overcoming the short-term stability issues of other M-N-C catalysts reported in the literature. The scalable and cost-effective synthesis approach paves the way for practical CO2 reduction applications.
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
(2023)
Article
Construction & Building Technology
Hailong Li, Xueyu Pang, Jian Zhang, Xian Shi
Summary: The mechanical behavior of a low-density cement under shale oil in-situ conversion conditions was studied in this paper. A series of tests were conducted to determine its physical and mechanical properties, and XRD and TGA tests were performed for composition evaluations after exposure to high temperatures. The results showed that the cement's strength was stabilized after 7 days at 50 degrees C, but deteriorated significantly at temperatures above 380 degrees C due to the decomposition of hydration products. The triaxial test results indicated that the mechanical properties were sensitive to confining pressure, and pore collapse was the main cause for the change in failure patterns from brittle to ductile.
CONSTRUCTION AND BUILDING MATERIALS
(2023)
Article
Thermodynamics
Lijian Leng, Tanghao Li, Hao Zhan, Muhammad Rizwan, Weijin Zhang, Haoyi Peng, Zequn Yang, Hailong Li
Summary: Machine learning algorithms were used to predict and control the relative content of nitrogen heterocyclic compounds in bio-oil (NH_Oil) produced from biomass pyrolysis. The results showed that machine learning has significant potential in addressing this issue and guiding experimental studies.
Article
Engineering, Electrical & Electronic
Bing Liu, Jamilu T. Baraya, Shitian Zhang, Maoyan Wang, Samira Nemati, Mengxia Yu, Guiping Li, Jun Xu, Xiaochuan Zhang, Yu Liu, Hailong Li
Summary: A fast and efficient frequency-domain finite element method is developed to simulate propagation characteristics of VLF waves in the Earth-ionosphere waveguide structure during the transition period between day and night. The method is accelerated using GPU-based parallel LU factorization method. A approach for determining the waveguide structure with the VLF transmitter and receiver locations is presented. The revised IRI model shows excellent agreement with measured data, providing a promising way to research VLF electromagnetic properties and improve prediction accuracy for VLF navigation and communication.
INTERNATIONAL JOURNAL OF NUMERICAL MODELLING-ELECTRONIC NETWORKS DEVICES AND FIELDS
(2023)
Article
Computer Science, Artificial Intelligence
Junqi Wang, Hailong Li, Gang Qu, Kim M. Cecil, Jonathan R. Dillman, Nehal A. Parikh, Lili He
Summary: A dynamic weighted hypergraph convolutional network (dwHGCN) framework is proposed in this study to learn features from dynamic hypergraphs. The model improves the learning capability of brain functional connectome by assigning larger weights to hyperedges with higher discriminative power and enhances the interpretability of the model by identifying highly active interactions among ROIs shared by a common hyperedge. Experimental results demonstrate the superiority of this model in classification tasks using functional magnetic resonance imaging (fMRI) data.
MEDICAL IMAGE ANALYSIS
(2023)
Article
Green & Sustainable Science & Technology
Ruiqi Cheng, Peng Yuan, Hailong Li
Summary: This study investigates whether the reduction in pollution emissions from exporting is related to the stringency of environmental regulation. Using the two control zones policy in China as a natural experiment, the study finds that Chinese manufacturing firms can significantly reduce their SO2 emissions intensity through exporting, but only in the firms regulated by the two control zones policy. The study confirms for the first time that the abatement effect of exporting is driven by stringent environmental regulations. Further analysis reveals that the abatement effect is mainly achieved through firm investment in source control technologies.
ENVIRONMENT DEVELOPMENT AND SUSTAINABILITY
(2023)
Article
Energy & Fuels
Jianping Yang, Xiangying Lu, Fanyue Meng, Hailong Li
Summary: This study investigates the dissolution behavior of overhaul slag in a molten salt system through thermodynamic calculation and experiments, and proposes a synergistic disposal strategy by utilizing the waste as a raw material in the aluminum electrolysis process.
Article
Energy & Fuels
Jianping Yang, Xiaolei Zhu, Zejian Ai, Lijian Leng, Hailong Li
Summary: This study adopted a catalytic pyrolysis approach with the participation of CaO for the reclamation disposal of oily sludge. The results demonstrate that this approach not only improves the yield and quality of pyrolysis oil, but also reduces the emission and mobility of heavy metals.
Article
Energy & Fuels
Wei Zheng, Zequn Yang, Jiefeng Chen, Weizhen He, Ruiyang Qin, Hongxiao Zu, Wenqi Qu, Jianping Yang, Lijian Leng, Hailong Li
Summary: Ti3C2 MXene/Cu2Se sorbent synthesized via a Lewis acid etching route combined with room-temperature selenization pathway shows excellent Hg0 adsorption performance, with higher adsorption capacity and uptake rate compared to other metal selenides. It also maintains outstanding adsorption performance under high temperature and is applicable to various fuel gas situations.
Article
Engineering, Environmental
Xinping Zhang, Yuxin Guo, Xiaoyang Liu, Shun-Yu Wu, Ya-Xuan Zhu, Shao-Zhe Wang, Qiu-Yi Duan, Ke-Fei Xu, Zi-Heng Li, Xiao-Yu Zhu, Guang-Yu Pan, Fu-Gen Wu
Summary: This study develops a nanotrigger HCFT for simultaneous photodynamic therapy and light-triggered ferroptosis therapy. The nanotrigger can relieve tumor hypoxia, induce enhanced photodynamic reaction, and facilitate the continuation of Fenton reaction, ultimately leading to lethal ferroptosis in tumor cells.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Olumide Bolarinwa Ayodele, Toyin Daniel Shittu, Olayinka S. Togunwa, Dan Yu, Zhen-Yu Tian
Summary: This study focused on the semihydrogenation of acetylene in an ethylene-rich stream using two alloyed Pt catalysts PtCu and PtCo. The PtCu catalyst showed higher activity and ethylene yield compared to PtCo due to its higher unoccupied Pt d-orbital density. This indicates that alloying Pt with Cu is more promising for industrial relevant SHA catalyst.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Guowei Chen, Wen-Cheng Chen, Yaozu Su, Ruicheng Wang, Jia-Ming Jin, Hui Liang, Bingxue Tan, Dehua Hu, Shaomin Ji, Hao-Li Zhang, Yanping Huo, Yuguang Ma
Summary: This study proposes an intramolecular dual-locking design for organic luminescent materials, achieving high luminescence efficiency and performance for deep-blue organic light-emitting diodes. The material also exhibits unique mechanochromic luminescence behavior and strong fatigue resistance.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Joren van Stee, Gregory Hermans, Jinu Joseph John, Koen Binnemans, Tom Van Gerven
Summary: This work presents a continuous solvent extraction method for the separation of cobalt and nickel in a millifluidic system using Cyphos IL 101 (C101) as the extractant. The optimal conditions for extraction performance and solvent properties were determined by investigating the effects of channel length, flow rate, and temperature. The performance of a developed manifold structure was compared to a single-channel system, and excellent separation results were achieved. The continuous separation process using the manifold structure resulted in high purity cobalt and nickel products.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Yan Xu, Jingai Jiang, Xinyi Lv, Hui Li, Dongliang Yang, Wenjun Wang, Yanling Hu, Longcai Liu, Xiaochen Dong, Yu Cai
Summary: A programmed gas release nanoparticle was developed to address the challenges in treating diabetic infected wounds. It effectively removes drug-resistant pathogens and remodels the wound microenvironment using NO and H2S. The nanoparticle can eliminate bacteria and promote wound healing through antibacterial and anti-inflammatory effects.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Tong Xia, Zhilin Xi, Lianquan Suo, Chen Wang
Summary: This study investigated a highly efficient coal dust suppressant with low initial viscosity and high adhesion-solidification properties. The results demonstrated that the dust suppressant formed a network of multiple hydrogen bonding cross-linking and achieved effective adhesion and solidification of coal dust through various chemical reactions.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Jinzhi Cai, Zhenshan Li
Summary: A density functional theory-based rate equation was developed to predict the gas-solid reaction kinetics of CaO carbonation with CO2 in calcium looping. The negative activation energy of CaO carbonation close to equilibrium was accurately predicted through experimental validation.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Jianxiong Chen, Fuhao Ren, Ningning Yin, Jie Mao
Summary: This study presents an economically efficient and easily implementable surface modification approach to enhance the high-temperature electrical insulation and energy storage performance of polymer dielectrics. The self-assembly of high-insulation-performance boron nitride nanosheets (BNNS) on the film surface through electrostatic interactions effectively impedes charge injection from electrodes while promoting charge dissipation and heat transfer.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Zijian Li, Zhaohui Yang, Shao Wang, Hongxia Luo, Zhimin Xue, Zhenghui Liu, Tiancheng Mu
Summary: This study reports a strategy for upgrading polyester plastics into value-added chemicals using electrocatalytic methods. By inducing the targeted transfer of *OH species, polyethylene terephthalate was successfully upgraded into potassium diformate with high purity. This work not only develops an excellent electrocatalyst, but also provides guidance for the design of medium entropy metal oxides.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Navneet Singh Shekhawat, Surendra Kumar Patra, Ashok Kumar Patra, Bamaprasad Bag
Summary: This study primarily focuses on developing a sulphur dyeing process at room temperature using bacterial Lysate, which is environmentally friendly, energy and cost effective, and sustainable. The process shows promising improvements in dye uptake and fastness properties.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Dengjia Shen, Hongyang Ma, Madani Khan, Benjamin S. Hsiao
Summary: This study developed cationic PVC nanofibrous membranes with high filtration and adsorption capability for the removal of bacteria and hexavalent chromium ions from wastewater. The membranes demonstrated remarkable performance in terms of filtration efficiency and maximum adsorption capacity. Additionally, modified nanofibrous membranes were produced using recycled materials and showed excellent retention rates in dynamic adsorption processes.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Xiaoyan Wang, Zhikun Wang, Ben Jia, Chunling Li, Shuangqing Sun, Songqing Hu
Summary: Inspired by photosystem II, self-supported Fe-doped NiCoP nanowire arrays modified with carboxylate were constructed to boost industrial-level overall water splitting by employing the concerted proton-coupled electron transfer mechanism. The introduction of Fe and carboxyl ligand led to improved catalytic activity for HER and OER, and NCFCP@NF exhibited long-term durability for overall water splitting.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Pengyao Yu, Ge Yang, Yongming Chai, Lubomira Tosheva, Chunzheng Wang, Heqing Jiang, Chenguang Liu, Hailing Guo
Summary: Thin LTA zeolite membranes were prepared through secondary growth of nano LTA seeds in a highly reactive gel, resulting in membranes with superior permeability and selectivity in gas separation applications.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Baiqin Zhou, Huiping Li, Ziyu Wang, Hui Huang, Yujun Wang, Ruichun Yang, Ranran Huo, Xiaoyan Xu, Ting Zhou, Xiaochen Dong
Summary: The use of machine learning to predict the performance of specific adsorbents in phosphate adsorption shows great promise in saving time and revealing underlying mechanisms. However, the small size of the dataset and insufficient detailed information limits the model training process and the accuracy of results. To address this, the study employs a fuzzing strategy that replaces detailed numeric information with descriptive text messages on the physiochemical properties of adsorbents. This strategy allows the recovery of discarded samples with limited information, leading to accurate prediction of adsorption amount, capacity, and kinetics. The study also finds that phosphate uptake by adsorbents is generally through physisorption, with some involvement of chemisorption. The framework established in this study provides a practical approach for quickly predicting phosphate adsorption performance in urgent scenarios, using easily accessible information.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Paula Alejandra Lamprea Pineda, Joren Bruneel, Kristof Demeestere, Lisa Deraedt, Tex Goetschalckx, Herman Van Langenhove, Christophe Walgraeve
Summary: This study evaluates the use of four esterified fatty acids and three vegetable oils as absorption liquids for hydrophobic VOCs. The experimental results show that isopropyl myristate is the most efficient liquid for absorbing the target VOCs.
CHEMICAL ENGINEERING JOURNAL
(2024)