Article
Biochemistry & Molecular Biology
Abdelrahman O. A. Eldenary, H. M. Abd El-Salam, Abeer Enaiet Allah
Summary: Concerns over heavy metals in wastewater and their impact on the environment and human health can be addressed through adsorption technology. This study developed efficient and cost-effective adsorbents, specifically chitosan-grafted polyacrylonitrile/ZnO, for the treatment of water contaminated with heavy metals. Various tests confirmed the morphological and structural properties of the materials, and the adsorption behavior of Fe(II) ions was studied. The adsorption process followed the Langmuir model and pseudo-second-order kinetics, suggesting a monolayer formation of Fe(II) over the adsorbent surface.
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
(2023)
Article
Environmental Sciences
James Friday Amaku, Segun A. Ogundare, Kovo G. Akpomie, Jeanet Conradie
Summary: ALU and KECA were used as adsorbents for the removal of toxic hexavalent chromium (Cr(VI)) from the aqueous phase. KECA showed a higher adsorption capacity and better reusability compared to ALU.
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
(2021)
Article
Green & Sustainable Science & Technology
Kadriye Esen Erden, Ramazan Donat
Summary: In this study, a composite SCX-37 biosorbent, made by mixing natural sepiolite and Cavex CA37 at certain ratios, is used for the biosorption of UO2+ (2) ions from a synthetic aqueous solution. The biosorption process is influenced by solution pH, ambient temperature, contact time, and UO2+ (2) ion concentration. The biosorption of UO2+ (2) ions on SCX-37 reaches equilibrium in 120 min with 97.56% efficiency at 30 degrees C and pH 4. The isotherms and thermodynamic values of the biosorption process are calculated, showing a high correlation between experimental results and all three isotherm models. The adsorption capacity is 41.39 mg g(-1) and the adsorption energy is 40.50 kJ mol(-1).
CLEAN-SOIL AIR WATER
(2023)
Article
Green & Sustainable Science & Technology
Abdulaziz G. Alghamdi, Zafer Alasmary
Summary: The transport of heavy metals to groundwater depends on soil characteristics such as carbonate and clay minerals, organic matter content, soil pH, etc. Most heavy metals in calcareous soils are precipitated as metal carbonate minerals, so their transport to groundwater is not expected. This study focuses on the adsorption and transport of lead (Pb) and copper (Cu) in calcareous soil in the presence of calcium carbonate.
Article
Chemistry, Multidisciplinary
Tao Feng, Zhixuan Fan, Si Wu, Lei Chen, Zishun Tian
Summary: Novel PAN/HAP composite nanofibrous membranes were successfully prepared via electrospinning and characterized. The membranes showed high adsorption capacity and reusability for Pb2+ removal.
NEW JOURNAL OF CHEMISTRY
(2022)
Article
Polymer Science
Opeoluwa Adeiga, Tarisai Velempini, Kriveshini Pillay
Summary: A novel polyaniline-decorated lignocellulose composite adsorbent, MNS-PANI, was prepared and showed high efficiency in the uptake of Cr(VI). The adsorption behavior of MNS-PANI was well-described by pseudo-second-order kinetics and Langmuir isotherm models, with endothermic and spontaneous uptake of Cr(VI). Moreover, the spent adsorbent exhibited efficient photocatalytic degradation of ciprofloxacin.
Article
Chemistry, Physical
Shraban Kumar Sahoo, Gagan Kumar Panigrahi, Jitendra Kumar Sahoo, Arun Kumar Pradhan, Aditya Kumar Purohit, Jyoti Prakash Dhal
Summary: Graphene-based nanocomposites were successfully developed using electrospinning technique for the removal of toxic hexavalent chromium ions from water, showing high adsorption capacity and fitting well with kinetic and isotherm models.
JOURNAL OF MOLECULAR LIQUIDS
(2021)
Article
Agricultural Engineering
Ravi Katiyar, Anil Kumar Patel, Thanh-Binh Nguyen, Reeta Rani Singhania, Chiu-Wen Chen, Cheng-Di Dong
Summary: This study found that seaweed-derived biochar showed high removal efficiency for Cu(II) in water, with Langmuir adsorption isotherm explaining the adsorption mechanisms. This indicates that waste biomass (seaweed) could be a valuable biological resource for removing heavy metals from various water bodies.
BIORESOURCE TECHNOLOGY
(2021)
Article
Environmental Sciences
S. Pavithra, Gomathi Thandapani, S. Sugashini, P. N. Sudha, Hussein H. Alkhamis, Abdulwahed F. Alrefaei, Mikhlid H. Almutairi
Summary: This study focused on removing heavy metals chromium and copper ions from wastewater using a biodegradable and cost-effective chitosan-based hydrogel composite. Experimental results revealed the optimum adsorption conditions and determined the adsorption isotherm models and kinetics.
Article
Environmental Sciences
Agathe Didier Antonio Koya, Mpho Cynthia Qhubu, Malvin Moyo, Vusumzi Emmanuel Pakade
Summary: This study used graft copolymerization to modify acid-washed Madacamia nutshell biomass with diethylenetriamine (DETA) and maleic anhydride (MA). The modified biomass contained polar and ionizable groups that were capable of adsorbing and removing hexavalent chromium (Cr(VI)) from aqueous solutions. Adsorption efficiency ranged from 70.9% to 81.7% over a wide pH range. The adsorption isotherm data fit the Freundlich model and the Sips isotherm model provided the best fit. The study demonstrates the potential of using DETA and MA modified Madacamia nutshell biomass for the removal of Cr(VI) from aqueous solutions.
ENVIRONMENTAL RESEARCH
(2022)
Article
Water Resources
Bilsen Tural, Erdal Ertas, Mehmet Guzel, Servet Tural
Summary: This study investigated the use of pumice from different regions of Turkey as supporting material for nanoscale zero-valent iron. The results showed that Diyarbakir pumice was more effective as a support material for nFe(0) compared to Bitlis pumice, with significantly increased iron content and stronger adsorption capacity for Cr(VI) ions.
APPLIED WATER SCIENCE
(2021)
Article
Chemistry, Multidisciplinary
Teerawat Laonapakul, Tanaratchanon Suthi, Yuichi Otsuka, Yoshiharu Mutoh, Patamaporn Chaikool, Prinya Chindaprasirt
Summary: The use of waste or natural resources to prepare adsorbent materials was studied in this research. The natural kaolin clay and hydroxyapatite synthesized from biogenic waste were investigated as defluoridation materials. The results showed that molded samples had better adsorption performance compared to powdered form, with a maximum fluoride adsorption capacity of 1.74 F- mg/g and an efficiency of 87%.
ARABIAN JOURNAL OF CHEMISTRY
(2022)
Article
Engineering, Chemical
Manish Sharma, Priya Sharma, Lalita Yadav, Vikash Chandra Janu, Ragini Gupta
Summary: Efficient removal and recovery of thorium from water resources is achieved using magnetically separable Glu@MNPs. The adsorption process follows Langmuir isotherm and pseudo-second-order equation. The high removal efficiency is due to the presence of various functional groups on Glu@MNPs surface. The optimized conditions from the composite design model match well with batch adsorption studies.
SEPARATION AND PURIFICATION TECHNOLOGY
(2023)
Article
Energy & Fuels
Weijun Shen, Luo Zuo, Tianran Ma, Cong Chen, Chaozhong Qin, Liu Yang, Kun Xie
Summary: Researchers conducted high-pressure isothermal adsorption experiments on deep shales from the Longmaxi Formation in southern China and found that the adsorbed gas and free gas in deep shales are influenced by temperature, pressure, and moisture. The research results provide a reference for evaluating shale gas reservoirs, estimating reserves in deep shales, and evaluating the adsorption and flow capacity of deep shale gas.
Article
Materials Science, Multidisciplinary
Henrik K. Hansen, Claudia Gutierrez, Natalia Valencia, Claudia Gotschlich, Andrea Lazo, Pamela Lazo, Rodrigo Ortiz-Soto
Summary: Heavy metal exposure from wastewater is a global environmental issue. Biosorption is a promising alternative for contaminant removal. This study investigated the operation parameters and biosorbent regeneration for copper adsorption. The results showed that Durvillaea antarctica algae had a higher copper retention capacity at pH 4.5-5.0, and sulfuric acid was the most efficient regenerating reagent. Particle size of 1.70-3.36 mm and a biosorbent mass-to-volume ratio of 10 g L-1 were desirable for diluted copper solutions (10 to 100 mg L-1).
Review
Immunology
Yogesh Sharma, Adesh K. Saini, Sheetal Kashyap, Gourav Chandan, Narinder Kaur, Vijai Kumar Gupta, Vijay Kumar Thakur, Vipin Saini, Reena V. Saini
Summary: miRNAs play crucial roles in regulating cellular activities and immune responses. Nanotechnology has been utilized to improve the stability and cellular uptake of miRNAs, paving the way for potential therapeutic applications in various diseases.
IMMUNOLOGIC RESEARCH
(2022)
Article
Biochemistry & Molecular Biology
Surbhi Kumawat, Yogesh Sharma, Sanskriti Vats, Sreeja Sudhakaran, Shivani Sharma, Rushil Mandlik, Gaurav Raturi, Virender Kumar, Nitika Rana, Amit Kumar, Humira Sonah, Rupesh Deshmukh
Summary: In this study, 15 SWEET genes were identified in the pomegranate genome, and their structure, classification, and expression dynamics were analyzed. The results suggest that SWEET genes are predominantly expressed in pomegranate peel and may exhibit differential expression under high salinity stress.
MOLECULAR BIOLOGY REPORTS
(2022)
Article
Multidisciplinary Sciences
Chetan Kumar Dotaniya, Brij Lal Lakaria, Yogesh Sharma, Bharat Prakash Meena, Satish Bhagwatrao Aher, Abhay Omprakash Shirale, Priya Gurav Pandurang, Mohan Lal Dotaniya, Ashis Kumar Biswas, Ashok Kumar Patra, Shish Ram Yadav, Madan Lal Reager, Ramesh Chandra Sanwal, Rajesh Kumar Doutaniya, Manju Lata
Summary: This study investigated the performance of chickpea crop under different nutrient management modules in a Vertisol. The results showed that integrated nutrient management modules had a positive impact on crop performance and productivity, as well as soil health. Among the various modules tested, the application of specific doses of organic and inorganic fertilizers to maize and chickpea showed the highest productivity and nutrient uptake in chickpea.
Article
Medicine, General & Internal
Y. Sharma, C. Horwood, P. Hakendorf, C. Thompson
Summary: After taking into account patients' frailty and other variables, there is no significant difference in clinical outcomes between hospitalized heart failure patients admitted under cardiology and general medicine.
QJM-AN INTERNATIONAL JOURNAL OF MEDICINE
(2022)
Article
Chemistry, Multidisciplinary
Zachary Corey, Henry H. Han, Kyeong Tae Kang, Xuejing Wang, Rebecca A. Lalk, Binod Paudel, Pinku Roy, Yogesh Sharma, Jinkyoung Yoo, Quanxi Jia, Aiping Chen
Summary: Mechanisms contributing to high carrier/electron mobility in oxide/SrTiO3 heterostructures have been investigated. It is found that the formation of a conducting substrate surface layer (CSSL) on STO substrate plays a critical role in enhancing the conductivity of LSTO/STO heterostructures. This CSSL is formed when an oxide layer (LSTO) is grown on STO, indicating that the oxide layer actively pulls oxygen from the substrate, leading to the formation of the CSSL. Oxygen transfer across the film/substrate interface during the synthesis of oxide heterostructures is emphasized as a critical factor in functional properties.
ADVANCED MATERIALS INTERFACES
(2022)
Article
Chemistry, Multidisciplinary
Alessandro R. Mazza, Elizabeth Skoropata, Yogesh Sharma, Jason Lapano, Thomas W. Heitmann, Brianna L. Musico, Veerle Keppens, Zheng Gai, John W. Freeland, Timothy R. Charlton, Matthew Brahlek, Adriana Moreo, Elbio Dagotto, Thomas Z. Ward
Summary: High entropy oxides provide a new approach to designing materials with tunable magnetic behaviors by exploiting strong local compositional disorder, leading to a transition from macroscopic order to frustration-driven dynamic spin interactions in magnetic systems.
Article
Biochemistry & Molecular Biology
Yogesh Sharma, Alexandra Popescu, Chris Horwood, Paul Hakendorf, Campbell Thompson
Summary: This study found an association between vitamin C deficiency and cognitive impairment in older hospitalised patients. The analysis showed that lower levels of vitamin C were significantly related to lower cognitive function, suggesting that vitamin C deficiency may increase the risk of cognitive impairment.
Article
Chemistry, Physical
Abhinav Tandon, Shalu Rani, Yogesh Sharma
Summary: Researchers have developed a novel binder-free magnesium manganese oxide nanofiber for lithium-ion batteries, which exhibits excellent electrochemical performance, high energy density, and good cyclic stability.
ACS APPLIED ENERGY MATERIALS
(2022)
Article
Chemistry, Physical
Meetesh Singh, Nagesh Kumar, Yogesh Sharma
Summary: Carbon additive, sucrose, was introduced to tailor the morphology of Li2MnSiO4. The addition of sucrose resulted in the formation of one-dimensional nanorods in the composite, which significantly improved the electronic conduction, lithium-ion diffusion, and reactivity. The composites exhibited a high initial charge capacity and excellent coulombic efficiency.
JOURNAL OF POWER SOURCES
(2022)
Article
Chemistry, Physical
Brahma Prakash Dubey, Asit Sahoo, Yogesh Sharma
Summary: In this study, a highly efficient garnet-type ion-conducting nanofibrous sheet was designed using the threshold percolation model and critical volume fraction requirement to tune the surface properties of the electrolyte membrane. The resulting solid-state lithium batteries showed excellent specific capacity and high capacity retention, making them promising for advanced energy storage technology.
JOURNAL OF POWER SOURCES
(2022)
Article
Medicine, General & Internal
Yogesh Sharma, Chris Horwood, Paul Hakendorf, Campbell Thompson
Summary: This study found an association between the use of HF-specific pharmacotherapy and improved clinical outcomes in frail HF hospitalised patients when compared to those who were not on treatment.
Proceedings Paper
Computer Science, Hardware & Architecture
Animesh Baranawal, Yogesh Simmhan
Summary: This study introduces optimization methods for ICM, which significantly improve algorithm runtime by reducing overheads such as message communication and time-warp shuffling.
PROCEEDINGS OF THE SEVENTEENTH EUROPEAN CONFERENCE ON COMPUTER SYSTEMS (EUROSYS '22)
(2022)
Proceedings Paper
Computer Science, Interdisciplinary Applications
Aakash Khochare, Yogesh Simmhan, Sameep Mehta, Arvind Agarwal
Summary: Serverless computing and FaaS have gained popularity for their ease of design, deployment, scaling, and billing on clouds. However, when used in scientific workflow composition and orchestration, they encounter limitations. In this paper, we propose a design of a Serverless Scientific Workflow Orchestrator that overcomes these challenges.
2022 IEEE 18TH INTERNATIONAL CONFERENCE ON E-SCIENCE (ESCIENCE 2022)
(2022)
Proceedings Paper
Computer Science, Hardware & Architecture
S. K. Prashanthi, Aakash Khochare, Sai Anuroop Kesanapalli, Rahul Bhope, Yogesh Simmhan
2022 IEEE 36TH INTERNATIONAL PARALLEL AND DISTRIBUTED PROCESSING SYMPOSIUM WORKSHOPS (IPDPSW 2022)
(2022)
Proceedings Paper
Computer Science, Hardware & Architecture
Prateeksha Varshney, Shriram Ramesh, Shayal Chhabra, Aakash Khochare, Yogesh Simmhan
Summary: This study proposes an innovative application model to declaratively specify queries to match micro-batch data streams from stream sources and trigger the distributed execution of data pipelines. Additionally, a resilient scheduling strategy is designed using advanced reservation on reliable fogs to guarantee dataflow completion within a deadline while minimizing the execution cost.
2022 22ND IEEE/ACM INTERNATIONAL SYMPOSIUM ON CLUSTER, CLOUD AND INTERNET COMPUTING (CCGRID 2022)
(2022)
Article
Engineering, Environmental
Xinping Zhang, Yuxin Guo, Xiaoyang Liu, Shun-Yu Wu, Ya-Xuan Zhu, Shao-Zhe Wang, Qiu-Yi Duan, Ke-Fei Xu, Zi-Heng Li, Xiao-Yu Zhu, Guang-Yu Pan, Fu-Gen Wu
Summary: This study develops a nanotrigger HCFT for simultaneous photodynamic therapy and light-triggered ferroptosis therapy. The nanotrigger can relieve tumor hypoxia, induce enhanced photodynamic reaction, and facilitate the continuation of Fenton reaction, ultimately leading to lethal ferroptosis in tumor cells.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Olumide Bolarinwa Ayodele, Toyin Daniel Shittu, Olayinka S. Togunwa, Dan Yu, Zhen-Yu Tian
Summary: This study focused on the semihydrogenation of acetylene in an ethylene-rich stream using two alloyed Pt catalysts PtCu and PtCo. The PtCu catalyst showed higher activity and ethylene yield compared to PtCo due to its higher unoccupied Pt d-orbital density. This indicates that alloying Pt with Cu is more promising for industrial relevant SHA catalyst.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Guowei Chen, Wen-Cheng Chen, Yaozu Su, Ruicheng Wang, Jia-Ming Jin, Hui Liang, Bingxue Tan, Dehua Hu, Shaomin Ji, Hao-Li Zhang, Yanping Huo, Yuguang Ma
Summary: This study proposes an intramolecular dual-locking design for organic luminescent materials, achieving high luminescence efficiency and performance for deep-blue organic light-emitting diodes. The material also exhibits unique mechanochromic luminescence behavior and strong fatigue resistance.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Joren van Stee, Gregory Hermans, Jinu Joseph John, Koen Binnemans, Tom Van Gerven
Summary: This work presents a continuous solvent extraction method for the separation of cobalt and nickel in a millifluidic system using Cyphos IL 101 (C101) as the extractant. The optimal conditions for extraction performance and solvent properties were determined by investigating the effects of channel length, flow rate, and temperature. The performance of a developed manifold structure was compared to a single-channel system, and excellent separation results were achieved. The continuous separation process using the manifold structure resulted in high purity cobalt and nickel products.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Yan Xu, Jingai Jiang, Xinyi Lv, Hui Li, Dongliang Yang, Wenjun Wang, Yanling Hu, Longcai Liu, Xiaochen Dong, Yu Cai
Summary: A programmed gas release nanoparticle was developed to address the challenges in treating diabetic infected wounds. It effectively removes drug-resistant pathogens and remodels the wound microenvironment using NO and H2S. The nanoparticle can eliminate bacteria and promote wound healing through antibacterial and anti-inflammatory effects.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Tong Xia, Zhilin Xi, Lianquan Suo, Chen Wang
Summary: This study investigated a highly efficient coal dust suppressant with low initial viscosity and high adhesion-solidification properties. The results demonstrated that the dust suppressant formed a network of multiple hydrogen bonding cross-linking and achieved effective adhesion and solidification of coal dust through various chemical reactions.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Jinzhi Cai, Zhenshan Li
Summary: A density functional theory-based rate equation was developed to predict the gas-solid reaction kinetics of CaO carbonation with CO2 in calcium looping. The negative activation energy of CaO carbonation close to equilibrium was accurately predicted through experimental validation.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Jianxiong Chen, Fuhao Ren, Ningning Yin, Jie Mao
Summary: This study presents an economically efficient and easily implementable surface modification approach to enhance the high-temperature electrical insulation and energy storage performance of polymer dielectrics. The self-assembly of high-insulation-performance boron nitride nanosheets (BNNS) on the film surface through electrostatic interactions effectively impedes charge injection from electrodes while promoting charge dissipation and heat transfer.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Zijian Li, Zhaohui Yang, Shao Wang, Hongxia Luo, Zhimin Xue, Zhenghui Liu, Tiancheng Mu
Summary: This study reports a strategy for upgrading polyester plastics into value-added chemicals using electrocatalytic methods. By inducing the targeted transfer of *OH species, polyethylene terephthalate was successfully upgraded into potassium diformate with high purity. This work not only develops an excellent electrocatalyst, but also provides guidance for the design of medium entropy metal oxides.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Navneet Singh Shekhawat, Surendra Kumar Patra, Ashok Kumar Patra, Bamaprasad Bag
Summary: This study primarily focuses on developing a sulphur dyeing process at room temperature using bacterial Lysate, which is environmentally friendly, energy and cost effective, and sustainable. The process shows promising improvements in dye uptake and fastness properties.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Dengjia Shen, Hongyang Ma, Madani Khan, Benjamin S. Hsiao
Summary: This study developed cationic PVC nanofibrous membranes with high filtration and adsorption capability for the removal of bacteria and hexavalent chromium ions from wastewater. The membranes demonstrated remarkable performance in terms of filtration efficiency and maximum adsorption capacity. Additionally, modified nanofibrous membranes were produced using recycled materials and showed excellent retention rates in dynamic adsorption processes.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Xiaoyan Wang, Zhikun Wang, Ben Jia, Chunling Li, Shuangqing Sun, Songqing Hu
Summary: Inspired by photosystem II, self-supported Fe-doped NiCoP nanowire arrays modified with carboxylate were constructed to boost industrial-level overall water splitting by employing the concerted proton-coupled electron transfer mechanism. The introduction of Fe and carboxyl ligand led to improved catalytic activity for HER and OER, and NCFCP@NF exhibited long-term durability for overall water splitting.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Pengyao Yu, Ge Yang, Yongming Chai, Lubomira Tosheva, Chunzheng Wang, Heqing Jiang, Chenguang Liu, Hailing Guo
Summary: Thin LTA zeolite membranes were prepared through secondary growth of nano LTA seeds in a highly reactive gel, resulting in membranes with superior permeability and selectivity in gas separation applications.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Baiqin Zhou, Huiping Li, Ziyu Wang, Hui Huang, Yujun Wang, Ruichun Yang, Ranran Huo, Xiaoyan Xu, Ting Zhou, Xiaochen Dong
Summary: The use of machine learning to predict the performance of specific adsorbents in phosphate adsorption shows great promise in saving time and revealing underlying mechanisms. However, the small size of the dataset and insufficient detailed information limits the model training process and the accuracy of results. To address this, the study employs a fuzzing strategy that replaces detailed numeric information with descriptive text messages on the physiochemical properties of adsorbents. This strategy allows the recovery of discarded samples with limited information, leading to accurate prediction of adsorption amount, capacity, and kinetics. The study also finds that phosphate uptake by adsorbents is generally through physisorption, with some involvement of chemisorption. The framework established in this study provides a practical approach for quickly predicting phosphate adsorption performance in urgent scenarios, using easily accessible information.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Paula Alejandra Lamprea Pineda, Joren Bruneel, Kristof Demeestere, Lisa Deraedt, Tex Goetschalckx, Herman Van Langenhove, Christophe Walgraeve
Summary: This study evaluates the use of four esterified fatty acids and three vegetable oils as absorption liquids for hydrophobic VOCs. The experimental results show that isopropyl myristate is the most efficient liquid for absorbing the target VOCs.
CHEMICAL ENGINEERING JOURNAL
(2024)