期刊
CHEMICAL COMMUNICATIONS
卷 50, 期 86, 页码 13052-13055出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc03644a
关键词
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资金
- MEXT, Japan
- JSPS
- Grants-in-Aid for Scientific Research [13J00320] Funding Source: KAKEN
The cobalt-catalyzed carboxylation of propargyl acetates with CO2 (1 atm) is described. The reaction proceeds at room temperature in the presence of Mn powder as a reducing reagent. Various propargyl acetates are converted to the corresponding carboxylic acids in good to high yields.
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