期刊
CHEMICAL COMMUNICATIONS
卷 50, 期 26, 页码 3488-3490出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc00497c
关键词
-
资金
- Irish Research Council
- ERC
- Science Foundation Ireland
Porphyrin rhodium(III) complexes accommodate one or two NHC ligands in the apical position, which leads to severe porphyrin distortion and dearomatization. The strain in the bis(carbene) complex induces facile carbene dissociation and the formation of a catalytically active site for alcohol oxidation.
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