4.7 Article

Zirconium complexes of bipyrrolidine derived salan ligands for the isoselective polymerisation of rac-lactide

期刊

CHEMICAL COMMUNICATIONS
卷 50, 期 100, 页码 15967-15970

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ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc07871c

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资金

  1. EPSRC [EP/G03768X/1]
  2. EPSRC UK National Service for Computational Chemistry Software [CHEM752]
  3. University of Bath
  4. EPSRC [EP/J003921/1] Funding Source: UKRI
  5. Engineering and Physical Sciences Research Council [EP/J003921/1, 1223532] Funding Source: researchfish

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Herein we report the synthesis and characterisation of a series of Zr(IV) 2,2' bipyrrolidine-salan derived complexes and their exploitation for the ring opening polymerisation of rac-lactide to afford highly isotactically enriched polymers.

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