期刊
CHEMICAL COMMUNICATIONS
卷 50, 期 28, 页码 3725-3728出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc00297k
关键词
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资金
- Singapore National Research Foundation [NRF-RF2008-10]
- Nanyang Technological University
Intermolecular Heck reaction of common alkyl halides, a long-standing problem in palladium catalysis, is realized with a simple Pd/dppf catalyst. Both primary and secondary alkyl halides are suitable for coupling with aromatic olefins. Single electron transfer from (dppf) Pd-degrees to alkyl halide initiated the catalytic cycle and gave alkyl radicals.
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