期刊
CHEMICAL COMMUNICATIONS
卷 50, 期 13, 页码 1564-1566出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc48339h
关键词
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资金
- National Science Foundation [NSF21072081]
- National Basic Research Program of China (973 Program) [2010CB8-33203]
- 111'' Project
- Program for Changjiang Scholars and innovative Research Team in the University [IRT1138]
A new and efficient metal-free cascade cyclization of 1,6-enynes with aldehydes is developed for the synthesis of tricyclic fluorene derivatives. The reaction involves a radical process and one C(sp(2))-C(sp(2)) and two C(sp(2))-C(sp(3)) bonds are formed simultaneously in one pot by using PivOH and TBHP.
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