期刊
CHEMICAL COMMUNICATIONS
卷 50, 期 69, 页码 9925-9928出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc03934c
关键词
-
资金
- Department of Science and Technology (DST), India
- CSIR, India
In situ formed acetal changes the course of Bronsted acid-catalyzed reaction of ortho-alkynylbenzaldehydes with arylalkynes altogether. By utilizing this, an efficient domino approach for the regiosetective synthesis of substituted benzo[a]fluorenes has been developed under mild reaction conditions. In situ formed acetal facilitates the intermolecular heteroallyne metathesis and subsequent trans to cis isomerization of a double bond to effect the intramolecular annotation.
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