期刊
CHEMICAL COMMUNICATIONS
卷 50, 期 27, 页码 3619-3622出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc00753k
关键词
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We present alpha-chloro amides as a new class of alpha-acetyl radical precursors, which undergo a tin-free, photoredox-catalysed intermolecular alpha-alkylation with various olefins exclusively in an anti-Markovnikov fashion. The reaction represents a reductive atom transfer radical addition (ATRA) and provides a series of alkylated amides in good yields.
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