期刊
CHEMICAL COMMUNICATIONS
卷 50, 期 3, 页码 323-325出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc47182a
关键词
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资金
- IISER Pune
- DST-SERB [SR/S1/OC-65/2012]
- CSIR
A novel 1,3-amino group migration strategy for the synthesis of acrylamidines is presented. Cu(I) catalyzed reaction of N,N-disubstituted propargylamine with tosylazide generates a highly reactive ketenimine intermediate which is trapped by a tethered amino group leading to the rearrangement reaction.
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