4.7 Article

Guest control of structure in porous organic cages

期刊

CHEMICAL COMMUNICATIONS
卷 50, 期 67, 页码 9465-9468

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ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc04158e

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资金

  1. EPSRC [EP/H000925/1]
  2. ERC [321156]
  3. EPSRC [EP/H000925/1] Funding Source: UKRI
  4. Engineering and Physical Sciences Research Council [EP/H000925/1] Funding Source: researchfish
  5. European Research Council (ERC) [321156] Funding Source: European Research Council (ERC)

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Two porous organic cages with different thermodynamic polymorphs were induced by co-solvents to interchange their crystal packing modes, thus achieving guest-mediated control over solid-state porosity. In situ crystallography allows the effect of the co-solvent guests on these structural interconversions to be understood.

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