期刊
CHEMICAL COMMUNICATIONS
卷 50, 期 34, 页码 4445-4447出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc00767k
关键词
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资金
- National Basic Research Program of China [2011CB808700]
- National Nature Science Foundation of China [21232006]
A method using quinidine and optically active binol-derived phosphoric acid as a cocatalyst to catalyze the asymmetric semipinacol rearrangement of 2,3-allenols forming optically active 3-bromo-3-enals that contain an all-carbon quaternary stereocenter has been developed. After some further treatments, the products with practical enantiomeric purity could be prepared.
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