期刊
CHEMICAL COMMUNICATIONS
卷 50, 期 36, 页码 4751-4754出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc01587h
关键词
-
资金
- Chinese Academy of Sciences
- National Natural Science Foundation of China [21002106, 21133011, 21373246]
The KI-catalyzed N-acylation of azoles via direct oxidative coupling of C-H and N-H bonds has been developed. It could be smoothly scaled up to gram synthesis of acyl azoles. The reaction occurred by the coupling of acyl radicals and azoles to form the acyl azole radical anion, followed by its further oxidation.
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