期刊
CHEMICAL COMMUNICATIONS
卷 50, 期 87, 页码 13292-13295出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc06136e
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资金
- EPSRC
- ERG
- World Premier International Research Center Initiative on Materials Nanoarchitectonics (WPI-MANA) from MEXT, Japan
Upon heating, lithium L-malate undergoes topotactic dehydration to form a phase containing the unsaturated fumarate ligand, in which the original 3-D framework remains intact. Insight into this unusual transformation has been obtained by single crystal X-ray diffraction, MAS-NMR, in situ powder X-ray diffraction and DFT calculations.
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