期刊
CHEMICAL COMMUNICATIONS
卷 50, 期 63, 页码 8709-8711出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc01135j
关键词
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资金
- 973 Program [2012CB725302]
- National Natural Science Foundation of China [21390400, 21025206, 21272180, 21302148]
- Research Fund for the Doctoral Program of Higher Education of China [20120141130002]
- Program for Changjiang Scholars and Innovative Research Team in University [IRT1030]
- U. S. Department of Energy, Office of Science, Office of Basic Energy Sciences [DE-AC02-06CH11357]
- Department of Energy
- MRCAT
Phenylzinc reagents prepared from various zinc halides show distinct kinetic features in the palladium-catalyzed Negishi-type oxidative coupling reaction, in which the phenylzinc reagent prepared from ZnI2 gives the highest rate. In situ infrared and X-ray absorption spectroscopy studies show that the higher reaction rate was observed for longer Zn-C bond distances.
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