期刊
CHEMICAL COMMUNICATIONS
卷 50, 期 69, 页码 9977-9980出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc03736g
关键词
-
资金
- World Premier International Center Initiative (WPI Initiative) on Materials Nanoarchitectonics, MEXT, Japan
- CREST of the Japan Science and Technology Agency (JST)
The swelling and exfoliation behavior of protonated layered oxides using an organo-phosphonium base, tetrabutylphosphonium hydroxide (TBPOH), was examined for the first time. The action of the aqueous solution induced massive interlayer expansion up to similar to 100-fold. The swollen crystals were immediately broken and completely exfoliated into unilamellar nanosheets in 1-2 h by shaking.
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