期刊
CHEMICAL COMMUNICATIONS
卷 49, 期 23, 页码 2344-2346出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc39074h
关键词
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A novel thiol functionalized bis-silane PMO precursor was synthesized by highly efficient thiol acid-ene chemistry between the double bonds of 1,2-(E)-bis(triethoxysilyl)ethene and thioacetic acid. After aminolysis the self-assembly process of the formed SH-precursor with Pluronic P123 under acidic conditions yields the first 100% thiol-PMO material with good structural ordering.
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