期刊
CHEMICAL COMMUNICATIONS
卷 49, 期 98, 页码 11569-11571出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc47695b
关键词
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资金
- INSA Rouen
- Rouen University
- CNRS
- EFRD
- Labex SynOrg [ANR-11-LABX-0029]
- European Union through a FEDER support engaged in region Haute-Normandie [34209, 33236]
An asymmetric organocatalysed decarboxylative protonation reaction allowed a straightforward synthesis of alpha-substituted isoxazolidin-5-ones from readily available 5-substituted Meldrum's acids. This process is initiated by an anionic formal (3+2) cycloaddition-fragmentation, generated in-situ from a sulfone-amide precursor which also served as a latent source of proton.
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