期刊
CHEMICAL COMMUNICATIONS
卷 49, 期 50, 页码 5648-5650出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc42655f
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资金
- Funding Program for Next Generation World-Leading Researchers from JSPS [220GR049]
- KAKENHI from MEXT [23750038]
- Grants-in-Aid for Scientific Research [23750038] Funding Source: KAKEN
We herein report the synthesis of a bis-2-pyridylidene palladium(II) complex as an isoelectronic structure of the well-known 2,2'-bipyridine complexes. One-pot or stepwise C-Cl oxidative addition followed by base-mediated C-H palladation of the chlorobipyridine dication to palladium(0) yielded the bis-2-pyridylidene palladium(II) carbonate smoothly.
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