期刊
CHEMICAL COMMUNICATIONS
卷 49, 期 75, 页码 8362-8364出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc44562c
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资金
- BRNS, India [2011/20/37C/13/BRNS]
- UGC-India
- CSIR-India
Selective hydrogenolysis of C-CN bonds can allow chemists to take advantage of ortho-directing ability, alpha-C-H acidity and electron withdrawing ability of the cyano group for synthetic manipulations. We have discovered hydrogenolysis of aryl and aliphatic cyanides under just 1 bar of hydrogen by using a nickel catalyst. This protocol was applied in the aryl cyanide directed functionalization reaction and alpha-substitution of benzyl cyanides.
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