期刊
CHEMICAL COMMUNICATIONS
卷 49, 期 40, 页码 4465-4467出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc40811f
关键词
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资金
- EC FP7 Project [X10D]
- Centre for Plastic Electronics at Imperial College London, Doctoral Training Centre [EP/G037515/1]
- International Collaborative Research Programme of Gyeonggi-do, Korea
- EPSRC [EP/I002936]
- NSF [CHE 1026664]
- University of Manchester
- Solvay
- BASF
- SUPERGEN
- Engineering and Physical Sciences Research Council [EP/I002936/1, EP/G015287/1] Funding Source: researchfish
- EPSRC [EP/G015287/1, EP/I002936/1] Funding Source: UKRI
A series of novel thiophene-flanked benzodipyrrolidone (BPT)-based alternating copolymers are synthesised, their optical and electrical properties evaluated. The BPT unit promotes a conjugated, planar polymer backbone, with a low bandgap, primarily due to low lying LUMO energy levels. Copolymerisation with thiophene exhibits well balanced ambipolar organic field-effect transistor performance, with electron and hole mobilities 0.1 and 0.2 cm(2) V-1 s(-1), respectively.
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