期刊
CHEMICAL COMMUNICATIONS
卷 49, 期 68, 页码 7519-7521出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc43797c
关键词
-
资金
- National Science Foundation Materials Research and Science Center on Polymers [DMR 0820506]
We show that ultrasound-induced mechanical force isomerizes an azobenzene centered within a poly(methyl acrylate) polymer from cis to trans configuration without cleaving the azo bond. The isomerization rate was not altered by the polarity of the solvent indicating that the isomerization occurs through a non-polar, inversion transition state.
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