期刊
CHEMICAL COMMUNICATIONS
卷 49, 期 19, 页码 1921-1923出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc38783f
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资金
- Latsis Foundation
The first enantioselective total syntheses of virosaine A and bubbialidine are described. Key transformations include the formation of a tetracyclic intermediate via an intramolecular aza-Michael addition, generation of a N-hydroxy-pyrrolidine through a Cope elimination and an intramolecular [1,3]-dipolar cycloaddition to generate a complex 7-oxa-1-azabicyclo[3.2.1]octane ring system.
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