期刊
CHEMICAL COMMUNICATIONS
卷 49, 期 39, 页码 4286-4288出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc37281a
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资金
- ICIQ Foundation
- European Research Council [ERC-277883]
- MICINN [CTQ2009-13840, CTQ2012-34054]
- MICINN for RyC fellowship
- MICINN for JdC fellowship
A formal gamma-alkynylation of ketones via Pd-catalyzed C-C bond-cleavage is presented. The method allows for the coupling of tert-cyclobutanols and bromoacetylenes, giving access to versatile alkynes that are beyond reach otherwise.
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