4.7 Article

In situ observation of carrier transfer in the Mn-oxide/Nb:SrTiO3 photoelectrode by X-ray absorption spectroscopy

期刊

CHEMICAL COMMUNICATIONS
卷 49, 期 71, 页码 7848-7850

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc43584a

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资金

  1. Japan Society for the Promotion of Science (JSPS) [22850015, 24750134]
  2. Keio Gijuku Academic Development Fund
  3. Keio Kogaku-kai Fund
  4. Ministry of Education, Culture, Sports, Science and Technology (MEXT)
  5. Grants-in-Aid for Scientific Research [24750134, 23550001, 22850015, 25106010] Funding Source: KAKEN

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The Mn-oxide/Nb:SrTiO3 photoelectrode for oxygen evolution reaction was investigated by in situ Mn K-edge XAFS spectroscopy under UV irradiation. The oxidization of the Mn oxide was observed via photoexcited carrier transfer, which results in the positive potential shift of the Mn oxide cocatalyst toward oxygen evolution reaction.

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