期刊
CHEMICAL COMMUNICATIONS
卷 48, 期 89, 页码 10990-10992出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc35329f
关键词
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A novel C(sp(3))-H amination of trimethylsilyl-substituted cyclopropenes is described. This C-H amination proceeds via a tandem regioselective ene reaction between cyclopropenes and azodicarboxylate to generate a hydrazodicarboxylate intermediate followed by its site-selective allylic transposition.
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