Article
Multidisciplinary Sciences
Daniel A. Strassfeld, Chia-Yu Chen, Han Seul Park, D. Quang Phan, Jin-Quan Yu
Summary: The functionalization of C-H bonds in organic molecules is a direct approach for chemical synthesis. Recent advances in catalysis have allowed various chemical groups to control and direct C(sp(3))-H activation, but alcohols, a common functionality, have remained difficult to react due to their low affinity for catalysts. This study describes ligands that enable alcohol-directed arylation of C(sp(3))-H bonds through charge balance and hydrogen-bonding interactions, thus enhancing substrate-catalyst affinity and enabling previously unknown reactivity.
Article
Chemistry, Organic
Liuzhou Gao, Xueting Liu, Guoao Li, Shengda Chen, Jia Cao, Guoqiang Wang, Shuhua Li
Summary: A metal-free silyl-pyridylation method for the synthesis of C-4-silylalkylated pyridines has been demonstrated. This method proceeds through a silyl radical addition/radical-radical coupling sequence and exhibits a broad substrate scope and excellent functional group compatibility, making it suitable for late-stage modification of bioactive molecules.
Article
Chemistry, Multidisciplinary
Juraj Konc, Valerio Sabatino, Ester Jimenez-Moreno, Eloah Latocheski, Laura Rodriguez Perez, Jason Day, Josiel B. Domingos, Goncalo J. L. Bernardes
Summary: This study reports a method for generating an active palladium species inside living cells and triggering bond-cleavage reactions to release biologically active molecules. These findings not only expand the toolbox of available bioorthogonal dissociative reactions, but also provide an additional strategy for controlling Pd-mediated reactions.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2022)
Article
Chemistry, Multidisciplinary
Harish S. Kunchur, Latchupatula Radhakrishna, Madhusudan K. Pandey, Maravanji S. Balakrishna
Summary: The new bisphosphine ligand exhibited unique reactivity with Pd(II), resulting in the formation of a 1,2-azaphospholene complex through a series of reactions. Mechanistic details were investigated using methods such as NMR spectroscopy, DFT calculations, and SCXRD analysis.
CHEMICAL COMMUNICATIONS
(2021)
Article
Chemistry, Multidisciplinary
Zhize Ou, Liu He, Yunyan Gao, Pingyi Li, Tianzhu Li, Jing Zhang, Yitao Dong, Weijuan Zhou, Yiqing Zhang
Summary: An allyl quaternary ammonium modified phenanthroimidazole derivative (AL-PPI) has been developed for the ratiometric detection of palladium, showing high sensitivity and selectivity towards Pd-0. The sensing mechanism is based on the Pd-0-catalyzed C-N bond cleavage of the N-allylpyridinium moiety in AL-PPI. With the assistance of TFP, the LOD of AL-PPI for Pd2+ is significantly improved, making it a promising tool for quantitative detection of palladium in real samples.
NEW JOURNAL OF CHEMISTRY
(2021)
Article
Chemistry, Organic
Hayato Fujimoto, Shisato Yamamura, Momoka Kusano, Mamoru Tobisu
Summary: We presented the phosphine-catalyzed 1,2-diacylation of alkynes using acyl fluorides and acylsilanes as acyl sources. The reaction relies on a formal oxidative addition-ligand metathesis-reductive elimination cycle based on phosphine redox catalysis, enabling the selective introduction of two different acyl groups into alkynes.
Article
Chemistry, Multidisciplinary
Zeqi Jiang, Sheng-Li Niu, Qiang Zeng, Qin Ouyang, Ying-Chun Chen, Qing Xiao
Summary: A novel Pd-catalyzed reaction has been developed for selective alkynylallylation of specific C-C sigma bonds in cyclopropenes, providing an efficient approach to highly functionalized dienynes. The reaction features fascinating atom and step economy and can produce gram-scale products using a simple, neutral, and low-cost catalytic system with high TONs. DFT calculations suggest that the success of the reaction relies on the selective insertion of cyclopropene double bonds into the C-Pd bond of ambidentate Pd complex and subsequent nonclassical beta-C elimination.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2021)
Article
Chemistry, Inorganic & Nuclear
Mahendra K. Sharma, Christoph Wolper, Stephan Schulz
Summary: Gallaphosphene reacts with polar X-H bonds at ambient temperature, showing selective 1,2 addition at the polar Ga-P double bond. The resulting complexes were characterized using IR and NMR spectroscopy, elemental analysis, and single-crystal X-ray diffraction.
DALTON TRANSACTIONS
(2022)
Article
Chemistry, Inorganic & Nuclear
Alain C. Tagne Kuate, Roger. A. Lalancette, Dirk Bockfeld, Matthias Tamm, Frieder Jakle
Summary: The research investigated the synthesis and chemical reactivity of Pd-0 complexes containing geometrically adaptable diferrocenylmercury-bridged diphosphine chelate ligands (L) and labile dba ligand. Trigonal LPd0(dba) complexes 2a and 2b were obtained upon treatment with Pd(dba)(2). A competition reaction revealed that 1b reacts faster than 1a with Pd(dba)(2).
DALTON TRANSACTIONS
(2021)
Article
Chemistry, Organic
Lin Zhu, Xiao Meng, Leipeng Xie, Qiuyang Shen, Wenyi Li, Lanlan Zhang, Chao Wang
Summary: In this study, a bidentate directing group-assisted Ni-catalyzed three component 1,2-carbosulfenylation reaction was reported, which allows for the transformation of unactivated alkenes using aryl/alkenylboronic acids and disulfide electrophiles. The reaction showed high levels of chemo- and regioselectivity and could introduce a wide range of aryl groups and sulfur moieties into homoallylic amines. Notably, it also enabled the synthesis of α,gamma-dibranched thiolamines with high diastereoselectivity and enantioselectivity.
ORGANIC CHEMISTRY FRONTIERS
(2022)
Article
Chemistry, Multidisciplinary
Jiaoyu Wu, Linqiang Li, Mengtian Liu, Lu Bai, Xinjun Luan
Summary: A novel Pd-0-catalyzed [2+2+1] annulation was proposed for the rapid assembly of tricyclic indoles in a single-step transformation. Experimental results showed that large tert-butyl and benzyl groups were selectively cleaved via an S(N)1 pathway in the presence of smaller alkyl groups.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2022)
Article
Chemistry, Organic
Zhi-Cheng Yu, You Zhou, Xiang-Long Chen, Jin-Tian Ma, Li-Sheng Wang, Yan-Dong Wu, An-Xin Wu
Summary: A reductive coupling reaction was established for the synthesis of diaryl 1,2-dicarbonyl compounds from aryl methyl ketones. The reaction involves C(CO)-C(sp3) bond cleavage and proceeds through an electron transfer process. Notably, this reaction is simple to operate, has mild reaction conditions, and is applicable to a wide range of substrates.
JOURNAL OF ORGANIC CHEMISTRY
(2022)
Article
Chemistry, Multidisciplinary
Yuanyuan Ping, Qi Pan, Ya Guo, Yongli Liu, Xiao Li, Minyan Wang, Wangqing Kong
Summary: Switchable selectivity in skeletal rearrangement can be achieved by controlling the migratory aptitude of different groups. Modifying the ligands on the metal catalyst and changing the oxidation states of the metal allow control over the migratory ability. This method enables site-selective activation and reorganization of C-C bonds and has been used for the synthesis of fluorine-containing scaffolds with medicinal relevance.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2022)
Article
Chemistry, Medicinal
Yuichi Kuboki, Shohei Ohno, Makoto Sako, Kenichi Murai, Mitsuhiro Arisawa
Summary: Migratory cycloisomerization using transition metal catalyst is a useful method for synthesizing substituted heterocyclic compounds. In this study, we achieved palladium-catalyzed migratory cycloisomerization of 3-o-alkynylphenoxy acrylic acid ester derivatives to obtain 2,3-disubstituted benzofurans. This is the first report of benzofuran synthesis with palladium-catalyzed cycloisomerization of C(sp(2))-O bond cleavage, expanding the scope of migratory groups for this reaction.
CHEMICAL & PHARMACEUTICAL BULLETIN
(2023)
Article
Multidisciplinary Sciences
Qiang Huang, Ga Young Lee, Jiayi Li, Chuan Wang, Rosalinda L. Zhao, Zixin Deng, K. N. Houk, Yi-Lei Zhao
Summary: Iodine-induced cleavage at phosphorothioate DNA has potential applications in detecting and sequencing bacterial DNA. However, the cleavage mechanism and specific selectivity at the modified site are not well established. This study reveals that iodine selectively binds to the sulfur atom of the phosphorothioate link and triggers P-O bond cleavage through phosphotriester-like hydrolysis. The cleavage process also results in unwanted P-S/P-O conversions and loss of the phosphorothioate handle.
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA
(2022)
Article
Chemistry, Multidisciplinary
Jan Schulz, Reike Clauss, Aleksandr Kazimir, Sieglinde Holzknecht, Evamarie Hey-Hawkins
Summary: The synthesis of B9-Phos ligands with two carboranyl moieties and bulky electron-donating substituents, previously deemed unattainable, is reported. The electrochemical properties of B9-Phos ligands were investigated, showing the ability of mesityl derivatives to form stabilized phosphoniumyl radical cations. The B9-Phos ligands possess a highly electron-releasing character surpassing that of alkyl phosphines and commonly used N-heterocyclic carbenes.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Article
Oncology
Annette G. Beck-Sickinger, Daniel P. Becker, Oksana Chepurna, Bhaskar Das, Sebastian Flieger, Evamarie Hey-Hawkins, Narayan Hosmane, Satish S. Jalisatgi, Hiroyuki Nakamura, Rameshwar Patil, Maria da Graca H. Vicente, Clara Vinas
Summary: This article summarizes current research on the development of boron delivery drugs for boron neutron capture therapy, which were presented and discussed at the National Cancer Institute (NCI) Workshop on Neutron Capture Therapy held on April 20-22, 2022. The most commonly used boron sources are icosahedral boron clusters attached to various molecules such as peptides, proteins, porphyrin derivatives, dendrimers, polymers, and nanoparticles, as well as encapsulated into liposomes. These boron clusters and/or carriers can be labeled with contrast agents, allowing for imaging techniques like PET, SPECT, and fluorescence to quantify tumor-localized boron and serve as theranostic agents.
CANCER BIOTHERAPY AND RADIOPHARMACEUTICALS
(2023)
Article
Pharmacology & Pharmacy
Philipp Stockmann, Lydia Kuhnert, Wencke Leinung, Cathleen Lakoma, Birte Scholz, Svetlana Paskas, Sanja Mijatovic, Danijela Maksimovic-Ivanic, Walther Honscha, Evamarie Hey-Hawkins
Summary: The overexpression of ATP-binding cassette (ABC) transporter proteins, particularly ABCG2, in cancer cells is a major cause of multidrug resistance (MDR) and the failure of chemotherapeutic treatments. Inhibition of ABCG2 activity during chemotherapy has the potential to reverse MDR and improve the efficacy of anti-cancer agents. However, the development of selective and non-toxic inhibitors of ABCG2 has been challenging, with limited success in clinical applications. This study focuses on the synthesis and evaluation of carboranyl quinazoline-based inhibitors of ABCG2, identifying a promising compound, DMQCd, which exhibits strong inhibitory effects and the ability to reverse MDR mediated by BCRP.
Article
Pharmacology & Pharmacy
Sebastian Braun, Svetlana Paskas, Markus Laube, Sven George, Bettina Hofmann, Peter Loennecke, Dieter Steinhilber, Jens Pietzsch, Sanja S. Mijatovic, Danijela Maksimovic-Ivanic, Evamarie Hey-Hawkins
Summary: In this study, carborane-containing dual COX-2/5-LO inhibitors were designed by incorporating metabolically stable, sterically demanding, and hydrophobic carboranes into existing inhibitors. Five carborane-containing derivatives showed high inhibitory activities towards COX-2 and 5-LO, with meta-carborane derivative 3 demonstrating higher anticancer activity compared to RWJ-63556. The accumulation of lipid droplets in cells indicated the blockage of COX-2 and 5-LO pathways, suggesting a promising approach for the design of potent dual COX-2/5-LO inhibitors.
ADVANCED THERAPEUTICS
(2023)
Article
Medicine, Research & Experimental
Jelena Matovic, Katayun Bahrami, Philipp Stockmann, Iris K. . Sokka, You Cheng Khng, Mirkka Sarparanta, Evamarie Hey-Hawkins, Jarkko Rautio, Filip S. Ekholm
Summary: Boron neutron capture therapy (BNCT) is a cancer treatment that uses boron delivery agents to selectively eradicate tumor cells. In this study, we focus on a GLUT1-targeting strategy to BNCT and synthesize carborane-bearing D-galactose, D-mannose, and D-allose as potential delivery agents. We find that these agents exhibit significantly improved boron delivery capacity compared to clinically approved agents in vitro, laying the groundwork for future preclinical assessment studies.
MOLECULAR PHARMACEUTICS
(2023)
Review
Biochemistry & Molecular Biology
Zeno Fickenscher, Evamarie Hey-Hawkins
Summary: Inspired by the role of multimetallic assemblies in enzyme catalysis, a wide range of heterobimetallic complexes have been developed for use in homogeneous catalysis. These complexes, starting from simple ones with s-donating and p-accepting ligands, have evolved into more complex systems over the past two decades. The presence of a second metal center in the active catalyst allows for new reaction pathways and significantly increased catalytic activity. This review focuses on the mechanistic aspects of heterobimetallic complexes in homogeneous catalysis, showcasing their versatility and the different types of interactions and reactions they enable.
Article
Biochemistry & Molecular Biology
Zeno B. G. Fickenscher, Peter Loennecke, Anna K. Mueller, Oldamur Holloczki, Barbara Kirchner, Evamarie Hey-Hawkins
Summary: Two heterometallic Mo,M' complexes (M' = Ir-III, Rh-III) were synthesized and characterized. They showed a significant synergistic effect, especially Mo and Ir, leading to a fourfold increase in catalytic activity compared to a binary mixture of the monometallic counterparts. The mechanism of CO2 hydrogenation to formate by a monometallic Ir-III catalyst was studied, revealing the importance of the metal-base adduct and inner-sphere hydride transfer.
Article
Biochemistry & Molecular Biology
Sebastian Braun, Sanja Jelaca, Markus Laube, Sven George, Bettina Hofmann, Peter Loennecke, Dieter Steinhilber, Jens Pietzsch, Sanja Mijatovic, Danijela Maksimovic-Ivanic, Evamarie Hey-Hawkins
Summary: Targeting inflammatory mediators and related pathways is a rational strategy for cancer treatment. Incorporating carboranes into dual COX-2/5-LO inhibitors shows promise, with compounds exhibiting high 5-LO inhibitory activities. However, carborane analogs demonstrate lower anticancer activity compared to related compounds in cell viability studies. R-830-Cb, a carborane-based analog, shows potential for further mechanistic and in vivo studies due to the advantages of boron cluster incorporation.
Article
Pharmacology & Pharmacy
Liridona Useini, Teodora Komazec, Markus Laube, Peter Loennecke, Jonas Schaedlich, Sanja Mijatovic, Danijela Maksimovic-Ivanic, Jens Pietzsch, Evamarie Hey-Hawkins
Summary: Nonsteroidal anti-inflammatory drugs (NSAIDs) are widely used for pain, fever, and inflammation, and have reported antitumor properties. Selectivity for the COX-2 isoform of NSAIDs is of high interest to reduce off-target effects. Modified NSAIDs using carborane clusters show altered selectivity profile and isonimesulide and its carborane derivatives exhibit stronger antitumor potential compared to nimesulide and isonimesulide. Additionally, replacement of the phenyl ring with a carborane moiety shifts the COX activity from nonactive to active compounds.
ADVANCED THERAPEUTICS
(2023)
Article
Pharmacology & Pharmacy
Ivana Predarska, Mohamad Saoud, Valentin Cepus, Evamarie Hey-Hawkins, Goran N. Kaluderovic
Summary: This article investigates the effects of oxaliplatin and its derivatives on different tumor types, and designs platinum(IV) platforms based on oxaliplatin to assess their antitumor capacity against various breast cancer cell lines.
ADVANCED THERAPEUTICS
(2023)
Article
Chemistry, Physical
Nils Koenig, Yokari Godinez-Loyola, Hendrik Weiske, Sergej Naumov, Peter Loennecke, Ralf Tonner-Zech, Cristian A. Strassert, Evamarie Hey-Hawkins
Summary: In this study, a facile synthetic strategy for obtaining propeller-rich molecules bearing a thieno[3,2-b]phosphole motif was reported via MnIII-mediated oxidative annulation reaction. All synthesized compounds showed aggregation-induced emission (AIE) characteristics, strong fluorescence in the solid state, and the photophysical properties were dependent on the substituents. The phosphinated thieno[3,2-b]phospholes exhibited a high degree of restrictions on intramolecular motions, leading to powerful solid-state light emitters with fluorescence quantum yields close to 100% and lifetimes up to 7.9 ns, even at room temperature.
CHEMISTRY OF MATERIALS
(2023)
Editorial Material
Chemistry, Multidisciplinary
Kyzgaldak Ramazanova, Peter Loennecke, Evamarie Hey-Hawkins
CHEMISTRY-A EUROPEAN JOURNAL
(2023)
Article
Oncology
Lydia Kuhnert, Robert Kuhnert, Menyhart B. Sarosi, Cathleen Lakoma, Birte K. Scholz, Peter Loennecke, Evamarie Hey-Hawkins, Walther Honscha
Summary: Chemotherapy is often hindered by multidrug resistance, and the inhibition of ABCG2 efflux transporter shows promise in overcoming drug resistance. This study successfully enhanced the affinity of baicalein towards ABCG2 by replacing the phenyl ring with a meta-carborane and adding three methoxy substituents. The modified compound demonstrated significant inhibitory effects on ABCG2-mediated drug resistance and holds potential for the development of efficient ABCG2 inhibitors.
MOLECULAR ONCOLOGY
(2023)
Article
Chemistry, Inorganic & Nuclear
Zeno B. G. Fickenscher, Leexander Torres-Texeira, Peter Loennecke, Evamarie Hey-Hawkins
Summary: A heterobimetallic [Mo degrees;CoIII] complex and the monometallic [CoIII] counterpart were synthesized and characterized. Both metals are electronically independent from each other. The catalytic activity of [Mo degrees;CoIII] and [CoIII] in homogeneous carbon dioxide hydrogenation to formate was studied, with [Mo degrees;CoIII] showing very low activity and [CoIII] showing no conversion.
INORGANICA CHIMICA ACTA
(2023)
Article
Biochemistry & Molecular Biology
Aleksandr Kazimir, Benedikt Schwarze, Peter Loennecke, Sanja Jelaca, Sanja Mijatovic, Danijela Maksimovic-Ivanic, Evamarie Hey-Hawkins
Summary: This study evaluates the potential of a copper-tamoxifen hybrid complex as a therapeutic candidate for breast cancer. The results show that the complex exhibits remarkable activity against different types of breast cancer cell lines, highlighting its efficacy through diverse mechanisms of action.
RSC MEDICINAL CHEMISTRY
(2023)
Review
Chemistry, Multidisciplinary
Dan He, Yawen Li, Fuwen Zhao, Yuze Lin
Summary: High trap density in organic solar cells leads to localized charge carriers and reduced carrier lifetime, limiting device efficiency. This feature article summarizes the recent advances of trap suppression by material design and device engineering.
CHEMICAL COMMUNICATIONS
(2024)
Review
Chemistry, Multidisciplinary
Olivier Monfort, Arshitha Madhusudhan, Martin Motola
Summary: This article presents the advantages of coupling photocatalysis and Fenton-based processes for environmental remediation and discusses their synergy. It critically examines the simultaneous triggering of these two processes and provides insights into research approaches. The study aims to enhance understanding of this complex process and highlight the potential integration of new catalysts in current wastewater treatment technology.
CHEMICAL COMMUNICATIONS
(2024)
Article
Chemistry, Multidisciplinary
Manideepa Dhar, Chittaranjan Mishra, Avijit Das, Uttam Manna
Summary: An approach of 'polymerization of monomers in its aggregated form' has been introduced to tailor the water wettability of fibrous and porous substrates, achieving hydrophobicity to superhydrophobicity transition, as well as patterned wettability. This facile chemical method provides a durable coating with adjustable and patterned wettability for various potential applications.
CHEMICAL COMMUNICATIONS
(2024)
Article
Chemistry, Multidisciplinary
Saswat Ranjan Bhoi, Chhanda Debnath, Shikha Gandhi
Summary: In this article, a novel catalytic reaction using Pd(0) and Bronsted acid is reported for the synthesis of biologically important imidazolidinone-fused N-heterocycles through redox-neutral intramolecular N-allylation of indoles and pyrroles with alkynes. This atom-economical method is applicable to a wide range of substrates and eliminates the need for leaving groups or oxidizing agents commonly used in traditional allylation reactions.
CHEMICAL COMMUNICATIONS
(2024)
Article
Chemistry, Multidisciplinary
Longkun Chen, Mingshuai Zhang, Meichen Liu, Zhuoyuan Liu, Yuetong Qiu, Zhilai Zhang, Fuchao Yu, Jiuzhong Huang
Summary: In this study, an efficient Rh(III)-catalyzed selective mono- and dual-C-H bond functionalization/cyclization with iodonium ylide as the sole coupling partner was demonstrated. Fused benzodiazepine skeletons were obtained in excellent yields, providing an improved approach to dual C-H unsymmetrical functionalization.
CHEMICAL COMMUNICATIONS
(2024)
Article
Chemistry, Multidisciplinary
Alice Kennett, Sven Epple, Gabriella van der Valk, Irene Georgiou, Evelyne Gout, Romain R. Vives, Angela J. Russell
Summary: This study presents the design and synthesis of sulfated disaccharide inhibitors based on IdoA(2S)-GlcNS(6S), which showed potent inhibition of Sulf-2. The results suggest that IdoA(2S)-GlcNS(6S) is the shortest fragment size required for effective inhibition of Sulfs, and a trisulfated disaccharide is identified as the minimal fragment size of heparan sulfate for effective endosulfatase inhibition.
CHEMICAL COMMUNICATIONS
(2024)
Article
Chemistry, Multidisciplinary
Mauro Garbini, Andrea Brunetti, Riccardo Pedrazzani, Magda Monari, Massimo Marcaccio, Giulio Bertuzzi, Marco Bandini
Summary: The self-adaptability of galvanostatic electrolysis was found to be helpful in a multistage chemo- and diastereoselective electrochemically promoted cyclodimerization of chalcones. Through a series of reductive events, densely functionalized cyclopentanes with five contiguous stereocenters were obtained (25 examples, yields up to 95%, dr values up to >20:1). Further experimental and electrochemical investigations indicated the crucial role of dynamic kinetic resolution of the aldol intermediate in the reaction mechanism.
CHEMICAL COMMUNICATIONS
(2024)
Article
Chemistry, Multidisciplinary
Dhananjay S. Nipate, Neha Meena, Prakash N. Swami, Krishnan Rangan, Anil Kumar
Summary: In this study, the synthesis of functionalized benzo[a]phenazines and indazolo[2,3-a]quinolines was achieved through Rh(III)-catalyzed oxidative annulation of 2-arylquinoxalines and 2-aryl-2H-indazoles with allyl alcohols. The method showed a wide substrate scope, excellent functional group tolerance, good to high yields of annulated products, and the capability for scaled-up synthesis. A tentative mechanism of the annulation reaction was proposed based on a preliminary mechanistic investigation.
CHEMICAL COMMUNICATIONS
(2024)
Article
Chemistry, Multidisciplinary
Ruonan Zhang, Abudukadi Tudi, Xia Yang, Xuping Wang, Zhihua Yang, Shujuan Han, Shilie Pan
Summary: A new lead tellurium borate material with a unique fundamental building block [B4O10] was synthesized and found to exhibit high birefringence. The structure-property relationship was discussed using first-principles calculations.
CHEMICAL COMMUNICATIONS
(2024)
Article
Chemistry, Multidisciplinary
Amresh Kumar Singh, Baishali Thakurta, Anupam Giri, Monalisa Pal
Summary: This study introduces three key concepts for the quick synthesis of large-scale high-quality 2D materials films and their utilization in device fabrication.
CHEMICAL COMMUNICATIONS
(2024)
Article
Chemistry, Multidisciplinary
Reina Hagiwara, Shun Nishimura, Kosuke Okeyoshi
Summary: A copolymer-conjugated nanocatalytic system has been developed to improve electron transfer and enhance photoinduced H2 generation.
CHEMICAL COMMUNICATIONS
(2024)
