期刊
CHEMICAL COMMUNICATIONS
卷 48, 期 33, 页码 3933-3935出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc31118f
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资金
- World Premier International Research Center Initiative on Materials Nano-architechtonics from MEXT, Japan
- Core Research for Evolutional Science and Technology (CREST) of JST, Japan [MSMT ME10149]
- European Regional Development Fund [CZ.1.05/1.1.00/02.0068]
Oxoporphyrinogens (OxPs) bind water molecules at pyrrolic NH and quinonoid carbonyl groups leading to visible colour changes due to variation in the pi-electronic structure of OxPs. Introduction of hydrophilic substituents at two pyrrole NH groups improves sensitivity to H2O, and one OxP derivative is a colorimetric indicator of trace H2O (similar to 50 ppm) in THF.
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