期刊
CHEMICAL COMMUNICATIONS
卷 48, 期 15, 页码 2152-2154出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc16943f
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资金
- National Natural Science Foundation of China [20925104, 21021062]
- National Basic Research Program of China [2010CB923303]
- Natural Science Foundation of Jiangsu Province [BK2010052]
- Ministry of Education of China [20090091110015]
- Scientific Research Foundation of Graduate School of Nanjing University [2010CL04]
The thermal or photochemical reactions of Cp*IrS2C2B10H10 (1) and aryl azides lead to C-C coupling via C(sp(3))-H activation in 2 as well as the formation of C-S bonds and new-type SSN pincer ligands in 3-8 through ortho-substituted electron-withdrawing group migration over an aryl ring.
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