期刊
CHEMICAL COMMUNICATIONS
卷 48, 期 32, 页码 3860-3862出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc18164a
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资金
- Grants-in-Aid for Scientific Research [22750201] Funding Source: KAKEN
A chiral gelator, RR- or SS-N,N'-diperfluorooctanoyl-1,2-diaminocyclohexane, gelated racemic 2-butanol. The gel was most stable at the racemic mixture, its stability lowered with the increase in the optical purity of the gelator. Notably, characteristic helically coiled fibrils were formed in the narrow region of enantiomer excess (ee = 0.2-0.4). Promotion effects of the antipodal enantiomers are proposed.
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