期刊
CHEMICAL COMMUNICATIONS
卷 48, 期 32, 页码 3809-3811出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc17163e
关键词
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资金
- Ministry of Education, Culture, Sports, Science and Technology [23655056]
- Japan Society for the Promotion of Science (JSPS) [23750067]
- Grants-in-Aid for Scientific Research [23655056, 23750067, 09F09738] Funding Source: KAKEN
Desulfurization of N,N-dimethylthioformamide (Me2NCHS) by hydrosilane has been achieved under photo irradiation in the presence of a methyl iron complex. The reaction sequences have been proposed, in which silyl migration from Fe to S of thioformamide triggers the cleavage of a C=S bond to give a carbene-iron complex. This intermediate was isolated and characterized by X-ray analysis.
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