期刊
CHEMICAL COMMUNICATIONS
卷 48, 期 93, 页码 11422-11424出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc34687g
关键词
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资金
- Australian Research Council
Crystalline (PMePh3)(2)[Cd-2(dhbq)(3)], (dhbq(2-) = deprotonated 2,5-dihydroxybenzoquinone, H(2)dhbq), attached to electrode surfaces, survives repeated cycles of reduction followed by re-oxidation when placed in contact with aqueous electrolyte media. The results afford encouragement that a range of coordination networks containing redox active connecting ligands and/or redox active metal centres may be reducible or oxidisable in the solid state.
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