期刊
CHEMICAL COMMUNICATIONS
卷 48, 期 53, 页码 6666-6668出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc31692g
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资金
- Haldor Topsoe company
- [14.740.11.0273]
- [02.740.11.0628]
A sandwich-type rhodium polyoxotungstate with unprecedented tetrarhodium-oxo core Na-12[(Rh-4(mu(3)-O)(2)(H2O)(2))(H2W9O33)(2)]center dot 38H(2)O (1) was obtained by hydrothermal reaction of rhodium(II) acetate and sodium tungstate; crystal structure was determined by X-ray diffractometry and was confirmed by W-183 NMR data; 1 is active in electrocatalytic water oxidation.
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