期刊
CHEMICAL COMMUNICATIONS
卷 48, 期 2, 页码 284-286出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc12260f
关键词
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资金
- Center for Advanced Molecular Photovoltaics (CAMP) of the King Abdullah University of Science and Technology [KUS-C1-015-21]
- Global Photonic Corporation
- Department of Energy's Energy Frontier Research Center [DE-SC0001011]
- National Science Foundation [CHE-0937015]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [0937015, 1048807] Funding Source: National Science Foundation
We report the synthesis and characterization of symmetric BODIPY dyads where the chromophores are attached at the meso position, using either a phenylene bridge or direct linkage. Both molecules undergo symmetry-breaking intramolecular charge transfer in the excited state, and the directly linked dyad serves as a visible-light-absorbing analogue of 9,9'-bianthryl.
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