期刊
CHEMICAL COMMUNICATIONS
卷 47, 期 3, 页码 1003-1005出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc03723k
关键词
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资金
- National Natural Science Foundation of China [20625205, 20772034, 20932002]
- National Basic Research Program of China (973 Program) [2011CB808603]
- Ministry of Education of China [20090172110014]
A new and general protocol for the synthesis of 1-acetoxy-1,3-dienes by an acetoxypalladation/Heck cross-coupling/beta-H elimination tandem process is described in which dioxygen is the terminal oxidant. Electron-rich and electron-deficient alkynes are both effective substrates in this system. It is the first example of acetoxypalladation of diarylalkynes.
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