期刊
CHEMICAL COMMUNICATIONS
卷 47, 期 46, 页码 12553-12555出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc15143f
关键词
-
资金
- Chinese Academy of Sciences
- National Natural Science Foundation of China [21002106, 21133011]
Rh-catalyzed C-H carbonylation of indoles under 1 atm of CO has been achieved. Various substituted indoles and indole with free N-H could be carboxylated with linear- and/or cyclic-alcohol to give the desired indole-3-carboxylates with up to 92% yield. A mechanism involving Rh-III initiated C-H metallation is proposed.
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