期刊
CHEMICAL COMMUNICATIONS
卷 47, 期 12, 页码 3643-3645出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc05714b
关键词
-
资金
- National Institutes of Health [GM-28939]
Cationic silane complex 2, catalyzes the hydrosilylation of epoxides and cyclic ethers to give the silyl-protected alcohols, regioselectively. A mechanistic study shows that the epoxide undergoes isomerization to the ketone, followed by hydrosilylation.
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