期刊
CHEMICAL COMMUNICATIONS
卷 47, 期 27, 页码 7851-7853出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc12052b
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资金
- Nanyang Technological University
- National Research Foundation of Korea (NRF) [2011-0009011]
- Korean government (MEST) [MEST 2009-0087013]
- 2nd phase BK21 program
A new stereoselective synthesis of trisubstituted alkenes is developed. Hydrophosphoryloxylation of haloalkynes provides Z-alkenyl halophosphates, which undergo Pd-catalyzed consecutive cross-coupling reactions to afford regio- and stereodefined trisubstituted alkenes.
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