期刊
CHEMICAL COMMUNICATIONS
卷 47, 期 26, 页码 7461-7463出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc12142a
关键词
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资金
- National Natural Science Foundation [20971110, 91022013]
- Ministry of Education of China [NCET-07-0765]
- Outstanding Talented Persons Foundation of Henan Province
- Ministry of Science and Technology of China [2009DFA50620]
The first hexagonal octadecanuclear Ag macrocycle [Ag-18(TTTMB)(12)](NO3)(18)center dot 30H(2)O has been hydrothermally synthesized. The outside and inner diameters of the unprecedented architecture are about 27.72(13) angstrom and 15.37(7) angstrom, respectively. This complex displays a huge increase in the intensity and lifetime of phosphorescence with decreasing temperature.
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