Article
Chemistry, Multidisciplinary
Ryo Yonemoto, Rieko Ueda, Akira Otomo, Yutaka Noguchi
Summary: In a light-emitting electrochemical cell (LEC), electrochemical doping facilitates charge injection and recombination emissions, resulting in high electroluminescence (EL) intensity at low driving voltages. In this study, a nanogap LEC (nano-LEC) consisting of a light-emitting polymer (F8BT) and an ionic liquid on a gold nanogap electrode was developed. The device demonstrated high EL intensity and a low threshold voltage at 300K. At low temperatures (<285K), the delayed components of the current and EL were strongly suppressed, indicating the nano-LEC as a promising approach for molecular-scale current-induced light sources.
Article
Chemistry, Inorganic & Nuclear
Babak Nemati Bideh, Hashem Shahroosvand, Mohammad Khaja Nazeeruddin
Summary: The study introduces two novel approaches to decrease the turn-on time of DR-LECs devices, based on molecularly engineered ruthenium phenanthroimidazole complexes. Results show that incorporating ionic methylpyridinium group and complexation of ruthenium emitter with Ag+ can significantly reduce the turn-on time and improve device efficiency.
INORGANIC CHEMISTRY
(2021)
Article
Materials Science, Multidisciplinary
Lorenzo Mardegan, Abhyuday Paliwal, Kassio P. S. Zanoni, Daniel Tordera, Henk J. Bolink
Summary: In this study, a transparent single layer light-emitting electrochemical cell (LEC) based on ionic transition metal complexes was successfully fabricated. The device showed high transparency, high luminance, and long lifetime, making it one of the highest performing single layer transparent electroluminescent devices.
ADVANCED OPTICAL MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Wen-Lu Kang, Yi-Ting Tsai, Yan-Cheng Ji, Rong-Huei Yi, Yun-Xin Wang, Hsiang-Ling Shen, Xuan-Jun Chen, Yu-Cheng Hsu, Chin-Wei Lu, Zu-Po Yang, Hai-Ching Su
Summary: This study demonstrates that separating the ion transport, electron injection and transport layer from the perovskite emissive layer is more effective in adjusting device carrier balance, leading to efficient perovskite LECs. Solution-processable perovskite/iTMC LECs offer a new approach to realizing high-efficiency perovskite LECs.
CHEMISTRY-A EUROPEAN JOURNAL
(2021)
Article
Multidisciplinary Sciences
Kosuke Yasuji, Tomo Sakanoue, Fumihiro Yonekawa, Katsuichi Kanemoto
Summary: The recombination between electrons and holes in electroluminescence processes has never been directly evaluated. In this study, the operation dynamics of light-emitting electrochemical cells were visualized with spectroscopic techniques, leading to a rapid device evaluation.
NATURE COMMUNICATIONS
(2023)
Article
Chemistry, Multidisciplinary
Lorenzo Mardegan, Chris Dreessen, Michele Sessolo, Daniel Tordera, Henk J. Bolink
Summary: The study investigated the use of a hyperbranched polymer blended with a Li salt as an electrolyte in PLECs, achieving excellent electroluminescent properties with high stability, long lifetime, peak efficiency, and short turn-on times. Additionally, the study examined the stability of the devices through measuring the photoluminescence during electroluminescent operation, showing quenching and immediate recovery of photoluminescence in vertically stacked devices.
ADVANCED FUNCTIONAL MATERIALS
(2021)
Article
Multidisciplinary Sciences
Vivian Wang, Shiekh Zia Uddin, Junho Park, Ali Javey
Summary: In this work, a highly multicolored light-emitting array with 49 different, individually addressable colors on a single chip is demonstrated. The array consists of pulsed-driven metal-oxide-semiconductor capacitors that generate electroluminescence from microdispensed materials, allowing arbitrary light spectra to be generated across a broad wavelength range. When combined with compressive reconstruction algorithms, these arrays can be used for compact spectroscopic measurements without diffractive optics. As an example, microscale spectral imaging of samples is demonstrated using a multiplexed electroluminescent array in conjunction with a monochrome camera.
Review
Chemistry, Multidisciplinary
Mona Sunaydih Alsaeedi
Summary: Cyclometallated iridium complexes possess excellent electrochemical and photophysical properties, and light-emitting electrochemical cells (LEECs) based on iridium containing ionic transition-metal complexes have shown promising potential as alternatives to conventional organic light-emitting diodes. This review provides a comprehensive overview of the current status of Ir-iTMC-based LEECs and discusses strategies for tuning emission characteristics and device stability.
JOURNAL OF SAUDI CHEMICAL SOCIETY
(2022)
Article
Materials Science, Multidisciplinary
Abhishake Goyal, Dongze Wang, Jun Gao
Summary: This study demonstrates planar polymer light-emitting electrochemical cells (LECs) with concentric circle electrodes. By varying the inner electrode radius from 1 to 3 mm with a fixed outer electrode radius of 6.8 mm, all cells can be activated at 360 K with a 40 V bias. The large electrode gap size allows for time-lapsed imaging of the in situ electrochemical p- and n-doping processes, and the concentric circular electrode configuration offers a cross sectional view of an LEC-based light-emitting fiber. Furthermore, the sensitivity of junction position to relative electrode radius indicates the strong coupling of p- and n-doping reactions.
ADVANCED MATERIALS TECHNOLOGIES
(2023)
Article
Materials Science, Multidisciplinary
Sophia Lipinski, Luca M. Cavinato, Thomas Pickl, Giulia Biffi, Alexander Poethig, Pedro B. Coto, Julio Fernandez-Cestau, Ruben D. Costa
Summary: Researchers report a novel design of red-emitting silver(I) complexes with efficient red emission and stable electrochemical behavior for thin-film lighting, addressing previous challenges in this field.
ADVANCED OPTICAL MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Abdelaziz Jouaiti, Lavinia Ballerini, Hsiang-Ling Shen, Ronan Viel, Federico Polo, Nathalie Kyritsakas, Stefan Haacke, Yu-Ting Huang, Chin-Wei Lu, Christophe Gourlaouen, Hai-Ching Su, Matteo Mauro
Summary: This study presents two binuclear heteroleptic Cu-I complexes with rigid chelating diphosphines and pi-conjugated 2,5-di(pyridin-2-yl)thiazolo[5,4-d]thiazole ligands. The complexes exhibit a large bathochromic shift of emission, allowing luminescence in the near-infrared (NIR) region. Photophysical and computational investigations confirm the radiative process and structural analysis reveals a unique doubly locked structure. These complexes are successfully used in NIR light-emitting electrochemical cells (LECs) and show potential for white-emitting LECs.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Article
Materials Science, Multidisciplinary
Joan Rafols-Ribe, Eduardo Gracia-Espino, Sandra Jenatsch, Petter Lundberg, Andreas Sandstrom, Shi Tang, Christian Larsen, Ludvig Edman
Summary: This study compared the performance of OLEDs and LECs under varying device temperatures and found that the temperature dependency differs between the two devices, with LECs being more affected by temperature changes. The deviation in behavior is attributed to the stronger positive temperature dependence of hole mobility compared to electrons in both OLEDs and LECs, leading to a shift in the emission zone towards the center of the active material.
ADVANCED OPTICAL MATERIALS
(2021)
Article
Chemistry, Applied
Hyung Jin Cheon, Chul Woong Joo, Da Yeon Lee, Gunel Huseynova, Jae-Hyun Lee, Jonghee Lee, Yun-Hi Kim
Summary: A new iridium complex based on (4-(3,5-dimethylphenyl)-2-(m-tolyl)pyridine) was synthesized for highly efficient orange phosphorescent organic light-emitting diodes (PhOLEDs). The introduction of a methyl substituent into the 4-position of the phenyl ring in a phenylpyridine chelating ligand was found to significantly improve the performance of PhOLEDs. The newly-synthesized iridium complex exhibited maximum external quantum and current efficiencies of 20.33% and 61.16 cd/A, respectively, with these values maintained even at high luminance levels.
Article
Chemistry, Multidisciplinary
Moon Chul Jung, John Facendola, Jongchan Kim, Daniel Sylvinson Muthiah Ravinson, Peter Djurovich, Stephen R. Forrest, Mark E. Thompson
Summary: The orientation of facial tris-cyclometalated iridium complexes in doped films can be controlled by altering the physical shape and electronic asymmetry in the molecular structure. Oblate iridium complexes have a net horizontal alignment in the thin films due to favorable van der Waals interaction with the host material, while chemical asymmetries introduced by substituents affect the oblate shapes and orientation of the molecules. The fluorinated patches in the substituted derivatives reinforce horizontal alignment during deposition, resulting in improved efficiency in organic light emitting diodes.
ADVANCED MATERIALS
(2021)
Article
Chemistry, Physical
Aditya Mishra, Stephen DiLuzio, Masoud Alahbakhshi, Austen C. Adams, Melanie H. Bowler, Jiyoung Moon, Qing Gu, Anvar A. Zakhidov, Stefan Bernhard, Jason D. Slinker
Summary: By utilizing a CsPbBr3 perovskite host and a novel ionic iridium complex guest, along with a polyelectrolyte, efficient light-emitting electrochemical cells (PeLECs) with significantly improved performance and enhanced luminance efficiency were achieved in this study.
CHEMISTRY OF MATERIALS
(2021)
Article
Biochemistry & Molecular Biology
Dalila Rocco, Alessandro Prescimone, Catherine E. Housecroft, Edwin C. Constable
Summary: This article describes the synthesis and characterization of two tritopic ligands containing a 2,2':6',2''-terpyridine (tpy) metal binding domain and either a 3,2':6',3''- or a 4,2':6',4''-tpy domain. The synthetic routes involved the [Pd(dppf)Cl2]-catalyzed coupling of a boronic ester-functionalized 2,2':6',2''-tpy with bromo-derivatives of 3,2':6',3''-tpy or 4,2':6',4''-tpy. The tritopic ligands preferentially bind Fe2+ ions and form iron(II) complexes with two peripheral 3,2':6',3''-tpy or 4,2':6',4''-tpy metal binding sites.
Article
Materials Science, Multidisciplinary
Youssef Atoini, Luca M. Cavinato, Julio Fernandez-Cestau, Yvonne Gmach, Daniel Van Opdenbosch, Ruben D. Costa
Summary: This study reports a sustainable and cost-effective blue-emitting MOF and its hybrid light-emitting diodes with emitters. These materials exhibit high stability under ambient operation, which is important for further development of luminescent MOFs.
ADVANCED OPTICAL MATERIALS
(2023)
Article
Materials Science, Multidisciplinary
Lucia Martinez-Goyeneche, Lidon Gil-Escrig, Daniel Tordera, Cristina Roldan-Carmona, Henk J. J. Bolink, Michele Sessolo
Summary: The research team developed a photodetector that can operate in broadband and narrowband modes depending on the illumination side. By depositing a low bandgap perovskite material on a transparent substrate, broadband response is achieved when illuminated from the bottom, while narrowband response is obtained when light is shined through the top perovskite based on the energy difference of the two perovskites. This study is significant for color discrimination and selective wavelength photodetection in imaging applications.
JOURNAL OF MATERIALS CHEMISTRY C
(2023)
Article
Energy & Fuels
Anderzon F. Palechor-Ocampo, Jorge Caram, Pedro Hierrezuelo-Cardet, Federico Ventosinos, Daniel Perez-del-Rey, Henk J. Bolink, Javier A. Schmidt
Summary: This study characterized the film of CH3NH3PbI3 deposited by thermal sublimation on different substrates using time-dependent photoconductivity measurements. The experimental results showed that the substrate had a significant effect on the behavior of the perovskite, and the photoconductivity was sensitive enough to probe these effects. Furthermore, a theoretical explanation based on the Shockley-Read-Hall statistics model was proposed, which explained the different photoconductivity responses by changing the relative values of the capture coefficients and the position of the Fermi level. It was suggested that the substrate changed the stoichiometry of the evaporated material, affecting the transient photoconductivity response.
Article
Energy & Fuels
Kassio P. S. Zanoni, Lucia Martinez-Goyeneche, Chris Dreessen, Michele Sessolo, Henk J. Bolink
Summary: To ensure reproducibility in perovskite photovoltaics, the sublimation control of organic ammonium halides is crucial. This study presents a reproducible procedure for the coevaporation of PbI2 and MAI using an evaporator chamber setup with two quartz crystal microbalances. The MAPbI(3)-QCM is used to indirectly monitor the MAI evaporation, avoiding fluctuating sublimation rates caused by variations in MAI purity, resulting in consistently high-performing solar cells over a period of one and a half years.
Article
Chemistry, Inorganic & Nuclear
Goncalo Valente, Maria Esteve-Rochina, Sergio P. C. Alves, Jose M. G. Martinho, Enrique Orti, Joaquin Calbo, Filipe A. Almeida Paz, Joao Rocha, Manuel Souto
Summary: This study presents an innovative synthesis method for producing highly crystalline and stable perylene-based coordination polymers. The materials have tunable optical and electrochemical properties, and exhibit high stability in the solid state.
INORGANIC CHEMISTRY
(2023)
Article
Materials Science, Multidisciplinary
Sophia Lipinski, Luca M. Cavinato, Thomas Pickl, Giulia Biffi, Alexander Poethig, Pedro B. Coto, Julio Fernandez-Cestau, Ruben D. Costa
Summary: Researchers report a novel design of red-emitting silver(I) complexes with efficient red emission and stable electrochemical behavior for thin-film lighting, addressing previous challenges in this field.
ADVANCED OPTICAL MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Mattia Nieddu, Marta Patrian, Sara Ferrara, Juan Pablo Fuenzalida Werner, Fabian Kohler, Eduardo Anaya-Plaza, Mauri A. Kostiainen, Hendrik Dietz, Jesus Ruben Berenguer, Ruben D. Costa
Summary: This work presents a new concept of using FP@SiO2 nanoparticles to address the issues of thermal emission quenching and H-transfer deactivation in biohybrid light-emitting diodes (Bio-HLEDs). By shielding the FP core with a SiO2-shell, stable and efficient high-power Bio-HLEDs were achieved, with a brightness of 100 lm W-1 for over 120 hours.
Article
Crystallography
Edwin C. C. Constable, Catherine E. E. Housecroft
Summary: Packing motifs in structurally characterized cis-[M(bpy)(2)X-2] coordination compounds were investigated. The compounds can be divided into two classes: non-solvated cis-[M(bpy)(2)X-2] moieties and those with additional lattice molecules. A recurring packing motif involving intermolecular p-stacking of bpy ligands and CHbpy...X contacts was observed, but slippage of stacked bpy units reduced the effectiveness of face-to-face interaction, making CHbpy...X contacts the dominant crystal-packing interaction. The prevalence of dimeric units versus 1D chains in the solid state was described.
Article
Chemistry, Multidisciplinary
Victor Garcia-Lopez, Niccolo Giaconi, Lorenzo Poggini, Joaquin Calbo, Amelie Juhin, Brunetto Cortigiani, Javier Herrero-Martin, Enrique Orti, Matteo Mannini, Miguel Clemente-Leon, Eugenio Coronado
Summary: The synthesis and characterization of a new Co(II) spin-crossover (SCO) complex based on a 4'-(4-carboxyphenyl)-2,2':6',2''-terpyridine ligand are described. The complex can be successfully grafted on the surface of silver while maintaining the spin-crossover behavior. Various techniques including AFM, MALDI-TOF MS, Raman spectroscopy, and XPS measurements confirmed the formation of a monolayer of intact molecules grafted onto the Ag surface through carboxylate groups. Raman spectroscopy, XPS, and XAS supported by first-principles calculations demonstrated a gradual spin transition of the deposited molecules with temperature, which is unprecedented for a monolayer of molecules directly grafted onto a metallic surface.
ADVANCED FUNCTIONAL MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Rafael Garcia-Meseguer, Enrique Orti, Inaki Tunon, J. Javier Ruiz-Pernia, Juan Arago
Summary: Polyethylene terephthalate (PET) is a commonly used polyester plastic in textiles and packaging, but it is also one of the most discarded after one use. The enzymatic biodegradation of PET has gained interest in recent years. The study investigated the molecular origin of the enhanced catalytic activity of FAST-PETase in PET degradation, finding that the rate-limiting reaction step for FAST-PETase is the acylation stage with a lower energy barrier compared to PETase. The enhancement is mainly attributed to the N233K mutation, inducing a chain folding that affects the catalytic triad and decreases the catalytic barrier.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2023)
Article
Chemistry, Multidisciplinary
Luis Leon-Alcaide, Javier Lopez-Cabrelles, Maria Esteve-Rochina, Enrique Orti, Joaquin Calbo, Bas Huisman, Michele Sessolo, Joao Waerenborgh, Bruno Vieira, Guillermo Minguez Espallargas
Summary: Bond breaking is a new tool for postsynthetically modifying the pore structure in metal-organic frameworks. In this study, the concept of clip-off chemistry is extended to ZIF-8, and the different stabilities of bonds between imidazolate and Zn and Fe metal atoms in heterometallic Fe-Zn-ZIF-8 are utilized. It is demonstrated that Fe centers can be selectively removed without affecting the backbone structure supported by Zn atoms. This strategy allows for the creation of mesopores within the highly stable ZIF-8 structure and opens up new possibilities for designing novel hierarchical porous frameworks.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2023)
Article
Chemistry, Physical
Joost W. C. Reinders, Cristina Roldan-Carmona, Henk J. Bolink, Francisco Palazon
Summary: This study reports on the fabrication of Mg(3)Bi(2) thin films under Mg-rich and Mg-poor conditions and demonstrates that Mg-deficient films show p-type conduction behavior with high power factor and thermoelectric figure of merit, while increasing the amount of Mg enables the formation of Mg-rich Mg3Bi2 films with n-type conduction and higher power factor and thermoelectric figure of merit at lower temperatures.
ACS APPLIED ENERGY MATERIALS
(2023)
Article
Chemistry, Physical
Rita B. Cevallos-Toledo, Delia Bellezza, Juan Ferrera-Gonzalez, Angelo Giussani, Enrique Orti, Maria Gonzalez-Bejar, Julia Perez-Prieto
Summary: This study demonstrates efficient cooperative sensitization (CS) upconversion of eosin Y (EOS) dianion after near-infrared (NIR) excitation with the use of Yb3+ (EOS-Yb) material. The emission of EOS dianion shows a linear dependence on EOS-Yb concentration and a quadratic dependence on laser power density. The emission process is non-sensitive to oxygen and has long lifetime in different solvents.
Article
Chemistry, Multidisciplinary
Diego J. Vicent, Manuel Perez-Escribano, Abel Cardenas-Valdivia, Ana Barragan, Joaquin Calbo, Jose I. Urgel, David Ecija, Jose Santos, Juan Casado, Enrique Orti, Nazario Martin
Summary: This study focuses on the investigation of relatively unknown tetrabromo-p-quinodimethanes (TBQs) as molecular building blocks. Five derivatives incorporating tetrabromo-anthraquinodimethane (TBAQ) units are showcased, revealing their warped geometry and complex NMR pattern. The study also assesses the sublimation, self-assembly, and reactivity of TBQ3 on Au(111).
Review
Chemistry, Multidisciplinary
Dan He, Yawen Li, Fuwen Zhao, Yuze Lin
Summary: High trap density in organic solar cells leads to localized charge carriers and reduced carrier lifetime, limiting device efficiency. This feature article summarizes the recent advances of trap suppression by material design and device engineering.
CHEMICAL COMMUNICATIONS
(2024)
Review
Chemistry, Multidisciplinary
Olivier Monfort, Arshitha Madhusudhan, Martin Motola
Summary: This article presents the advantages of coupling photocatalysis and Fenton-based processes for environmental remediation and discusses their synergy. It critically examines the simultaneous triggering of these two processes and provides insights into research approaches. The study aims to enhance understanding of this complex process and highlight the potential integration of new catalysts in current wastewater treatment technology.
CHEMICAL COMMUNICATIONS
(2024)
Article
Chemistry, Multidisciplinary
Manideepa Dhar, Chittaranjan Mishra, Avijit Das, Uttam Manna
Summary: An approach of 'polymerization of monomers in its aggregated form' has been introduced to tailor the water wettability of fibrous and porous substrates, achieving hydrophobicity to superhydrophobicity transition, as well as patterned wettability. This facile chemical method provides a durable coating with adjustable and patterned wettability for various potential applications.
CHEMICAL COMMUNICATIONS
(2024)
Article
Chemistry, Multidisciplinary
Saswat Ranjan Bhoi, Chhanda Debnath, Shikha Gandhi
Summary: In this article, a novel catalytic reaction using Pd(0) and Bronsted acid is reported for the synthesis of biologically important imidazolidinone-fused N-heterocycles through redox-neutral intramolecular N-allylation of indoles and pyrroles with alkynes. This atom-economical method is applicable to a wide range of substrates and eliminates the need for leaving groups or oxidizing agents commonly used in traditional allylation reactions.
CHEMICAL COMMUNICATIONS
(2024)
Article
Chemistry, Multidisciplinary
Longkun Chen, Mingshuai Zhang, Meichen Liu, Zhuoyuan Liu, Yuetong Qiu, Zhilai Zhang, Fuchao Yu, Jiuzhong Huang
Summary: In this study, an efficient Rh(III)-catalyzed selective mono- and dual-C-H bond functionalization/cyclization with iodonium ylide as the sole coupling partner was demonstrated. Fused benzodiazepine skeletons were obtained in excellent yields, providing an improved approach to dual C-H unsymmetrical functionalization.
CHEMICAL COMMUNICATIONS
(2024)
Article
Chemistry, Multidisciplinary
Alice Kennett, Sven Epple, Gabriella van der Valk, Irene Georgiou, Evelyne Gout, Romain R. Vives, Angela J. Russell
Summary: This study presents the design and synthesis of sulfated disaccharide inhibitors based on IdoA(2S)-GlcNS(6S), which showed potent inhibition of Sulf-2. The results suggest that IdoA(2S)-GlcNS(6S) is the shortest fragment size required for effective inhibition of Sulfs, and a trisulfated disaccharide is identified as the minimal fragment size of heparan sulfate for effective endosulfatase inhibition.
CHEMICAL COMMUNICATIONS
(2024)
Article
Chemistry, Multidisciplinary
Mauro Garbini, Andrea Brunetti, Riccardo Pedrazzani, Magda Monari, Massimo Marcaccio, Giulio Bertuzzi, Marco Bandini
Summary: The self-adaptability of galvanostatic electrolysis was found to be helpful in a multistage chemo- and diastereoselective electrochemically promoted cyclodimerization of chalcones. Through a series of reductive events, densely functionalized cyclopentanes with five contiguous stereocenters were obtained (25 examples, yields up to 95%, dr values up to >20:1). Further experimental and electrochemical investigations indicated the crucial role of dynamic kinetic resolution of the aldol intermediate in the reaction mechanism.
CHEMICAL COMMUNICATIONS
(2024)
Article
Chemistry, Multidisciplinary
Dhananjay S. Nipate, Neha Meena, Prakash N. Swami, Krishnan Rangan, Anil Kumar
Summary: In this study, the synthesis of functionalized benzo[a]phenazines and indazolo[2,3-a]quinolines was achieved through Rh(III)-catalyzed oxidative annulation of 2-arylquinoxalines and 2-aryl-2H-indazoles with allyl alcohols. The method showed a wide substrate scope, excellent functional group tolerance, good to high yields of annulated products, and the capability for scaled-up synthesis. A tentative mechanism of the annulation reaction was proposed based on a preliminary mechanistic investigation.
CHEMICAL COMMUNICATIONS
(2024)
Article
Chemistry, Multidisciplinary
Ruonan Zhang, Abudukadi Tudi, Xia Yang, Xuping Wang, Zhihua Yang, Shujuan Han, Shilie Pan
Summary: A new lead tellurium borate material with a unique fundamental building block [B4O10] was synthesized and found to exhibit high birefringence. The structure-property relationship was discussed using first-principles calculations.
CHEMICAL COMMUNICATIONS
(2024)
Article
Chemistry, Multidisciplinary
Amresh Kumar Singh, Baishali Thakurta, Anupam Giri, Monalisa Pal
Summary: This study introduces three key concepts for the quick synthesis of large-scale high-quality 2D materials films and their utilization in device fabrication.
CHEMICAL COMMUNICATIONS
(2024)
Article
Chemistry, Multidisciplinary
Reina Hagiwara, Shun Nishimura, Kosuke Okeyoshi
Summary: A copolymer-conjugated nanocatalytic system has been developed to improve electron transfer and enhance photoinduced H2 generation.
CHEMICAL COMMUNICATIONS
(2024)