期刊
CHEMICAL COMMUNICATIONS
卷 47, 期 1, 页码 421-423出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc02244f
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资金
- Cancer Society of New Zealand
gem-Dibromocyclopropane 1, prepared from tri-O-benzyl-D-glucal, undergoes thermal and silver-promoted ring expansion in the presence of alcohols to give substituted oxepines. With further heating, ring contraction to highly substituted tetrahydrofurans follows. These represent C-furanosides, potentially useful as precursors to C-nucleosides and other carbohydrate mimics.
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