期刊
CHEMICAL COMMUNICATIONS
卷 47, 期 27, 页码 7611-7613出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc12060c
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资金
- Division of Chemical Sciences, Geosciences, and Biosciences, Office of Basic Energy Sciences, U.S. Department of Energy
- Robert A. Welch Foundation [F-1018]
- Korean WCU [R32-2010-10217-0]
meso-Octamethylcalix[4]pyrrole (C4P) enhances sulfate selectivity in solvent extraction by Aliquat (R) 336N, an effect ascribed to the supramolecular preorganization and thermodynamic stability imparted by insertion of the methyl group of the Aliquat cation into the cup of C4P in its cone conformation.
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