期刊
CHEMICAL COMMUNICATIONS
卷 47, 期 28, 页码 7953-7955出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc12520f
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资金
- DFG (Deutsche Forschungsgemeinschaft)
The 'dipeptide extended' guanidiniocarbonyl pyrrole carboxylate zwitterion GCP-Phe-Phe 1 forms stable dimers in DMSO. However, dimerization is highly stereoselective. Only homochiral dimers are formed and the (L,L)center dot(L,L) dimer (K(dim) > 10(5) M(-1)) is significantly more stable by a factor of 10(3) than the diastereomeric (D,L)center dot(D,L) dimer (K(dim) = 120 M(-1)).
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