期刊
CHEMICAL COMMUNICATIONS
卷 46, 期 9, 页码 1449-1451出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b919836a
关键词
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资金
- MOST [2006CB932904, 2007CB815304, 2010CB933501]
- National Natural Science Foundation of China [20873150, 20821061, 50772113]
- Chinese Academy of Sciences [KJCX2-YW-M05, KJCX2-YW-319]
- Natural Science Foundation of Fujian Province [2007HZ0001-1]
Presented here is a homochiral three-dimensional diamondoid framework material, [Zn(AMTD)(2)](n) generated through an unusual spontaneous asymmetrical crystallization from achiral precursors without any enantiopure additives, which first demonstrates that symmetry breaking could be driven by the cooperation of twisted framework topology and an asymmetrical ligand.
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