期刊
CHEMICAL COMMUNICATIONS
卷 46, 期 17, 页码 3007-3009出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c001495h
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资金
- National Research Foundation of Korea [NRF 31200900000001826]
- BK21
2-(3-Benzyloxy)prop-1-ynyl)benzaldehyde with PtCl(2) in toluene would form Pt-pyryliums that underwent [3+2] cycloaddition with alkenes to the oxygen-bridged (5H-benzo[7]annulen-5-ylidene) platinum(II) intermediates with good stereoselectivities. Their tandem rearrangement afforded diverse types of polycycles depending on the electronic nature of the alkenes.
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